简介:Synchrotronradiationsmall-angleX-rayscattering(SAXS)andtheviscositytechniquewereusedtoinvestigatetheeffectofdissolvedCO2intolueneontheconformationofpolystyrene(PS)inthesolution.TheviscosityofPSsolutiondecreasesfasterwithincreasingantisolventCO2pressurethanthatofthesolventintheabsenceofthepolymer.theintrinsicviscosity[η]calculatedusingthewellknownHugginsequationdecreaseswithantisolventpressure.ItwasfoundthatthesecondvirialcoefficientA2andtheapparentmean-squareradiusofgyration^1/2decreaseswithpressureofantisolventCO2.AllthesephenomenacanbeattributedtotheshrinkofPSchaininthecourseofaddingthegasantisolventbecausetheintercationbetweenthepolymerandsolventbecomesweaker.Thevalues^1/2atdifferentpressuresobtainedfromSAXSdataagreereasonablywiththosecalculatedfromFlorytheoryusingtheviscositydatadeterminedinthiswork.ThisimpliesthatFlorytheory,whichhasbeenusedwidelyforthesolutionsofpolymersinliquidsolvents,isalsoapplicabletothepolymersolutionwithgasantisolvent.
简介:ForquadraticnumberfieldsF=Q(√2pl…pt-1)withprimespj≡1mod8,theauthorsstudytheclassnumberandthenormofthefundamentalunitofF.TheresultsgeneralizenicelywhathasbeenfamiliarforthefieldsQ(√2p)withaprimep≡1mod8,includingdensitystatements.Andtheresultsarestatedintermsofthequadraticformx2+32y2andillustratedintermsofgraphs.
简介:在介绍B.VANROOTSELAAR的解方程组x′=Ax的一种新方法的基础上,对矩阵F(0)求法作了补充,对照以往通常的解法,分析了它的优越性.文章用完全开放性的Maple语言程序在计算机上实现了这种方法的应用,并通过生动的例子说明了同样是借助计算机强大的计算功能,新的解法在速度上要提高上百倍,更有实用价值.
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简介:Inthisarticle,wetaketheX(5568)asthediquark-antidiquarktypetetraquarkstatewiththespin-parityJ~P=0~+,constructthescalar-diquark-scalar-antidiquarktypecurrent,carryouttheoperatorproductexpansionuptothevacuumcondensatesofdimension-10,andstudythemassandpoleresidueindetailswiththeQCDsumrules.WeobtainthevalueM_X=(5.57±0.12)GeV,whichisconsistentwiththeexperimentaldata.ThepresentpredictionfavorsassigningtheX(5568)tobethescalartetraquarkstate.
简介:主要考虑1+1维Boussinesq系统的一个Darboux变换,反复利用该Darboux变换,可以从该系统的一个已知解出发,通过代数运算和求导运算得到系统的新解.
简介:Theinsertionof1,1-bis(1′-naphthyl)ethylenemonomerunitintotheactivepolystyrenechainendgreatlydecreasedthereactivityoftheactivechainendtothecarbonylgroup,andallowedthepolymericchainendtoreactonlywiththedoublebondinN-methacryloylcaprolactam,resultinginN-acylcaprolactamfunctionalizedpolystyrenein100%conversion.Newdiblockcopolymerofpolystyrenewithpolycaprolactamwassynthesizedbydirectreactionofthefunctionalizedpolymerwithcaprolactamwithoutaddingadditionalalkalimetalortheircaprolactamsalts.
简介:Aseriesofnovel1H-benzimidazol-1-ylacetatesand1H-benzimidazol-1-ylpropionatescontaining1H-1,2,4-triazolemoietyweresynthesizedundermicrowaveirradiationbymulti-stepreactions,inyieldsof87-94%.TheirinvitroantifungalactivitiesagainstBotrytiscinereaandSclerotiniasclerotiorumwereevaluatedbymycelialgrowthratemethod.AllthetargetcompoundsexhibithighactivitiesagainstB.cinereawiththeEC50valuesof7.96-21.74μg/mL,higherthanthatofcarbendazim.
简介:Anewseriesofliquidcrystalscomprisingeightheterocyclicisoflavoneesters,7-alkanoyloxy-3-[4’-(3-methylbutyloxyphenyl)]-4H-1-benzopyran-4-onesexhibitingenantiotropicnematic(N)andsmecticC(SmC)phasesweresynthesizedandinvestigated.Themesomorphicpropertiesofallderivativeswereinvestigatedbymeansofdifferentialcalorimetryandpolarizedopticalmicroscopy.WideangleX-raydiffractiontechniquewasemployedtoinvestigatethemolecularpackingassociatedwiththeintermolecularinteractionaswellasthecorrelationbetweenthethermalbehaviourofthesecompoundswiththeiranisotropypropertieswithinamesophase.