简介:运用定制的聚偏四氟乙烯(PVDF)压电传感器,直接测量爆炸载荷下UHMWPE层叠无纬布和PU基体的UHMWPE复合材料内部冲击波压力峰值,对其冲击波衰减特性进行了实验研究.实验结果表明:UHMWPE复合材料对爆炸冲击波有很好的衰减作用,含有PU基体的UHMWPE复合材料比UHMWPE层叠无纬布对爆炸冲击波有更好的衰减效果.UHMWPE复合材料具有轻质、吸收冲击波效率高等特性,在爆炸冲击波防护领域有很好的应用前景.
简介:UltraHighMolecularWeightPolyethylene(UHMWPE)hasbeenwidelyusedasabearingmaterialforartificialjointreplacementoverfortyyears.Itisusuallycrosslinkedbygammaraysirradiationbeforeitsimplantationintohumanbody.Inthisstudy,UHMWPEandUHMWPE/nano-hydroxyapatite(n-HA)compositewerepreparedbyvacuumhot-pressingmethod.Thepreparedmaterialswereirradiatedbygammaraysinvacuumandmoltenheattreatedinvacuumjustafterirradiation.Theeffectoffillingn-HAwithgammairradiationontribologicalpropertiesofUHMWPEwasinvestigatedbyusingfrictionandwearexperimentalmachine(modelMM-200)underdeionizedwaterlubrication.Micro-morphologyofwornsurfacewasobservedbymetallographicmicroscope.Contactangleandhardnessofthematerialswerealsomeasured.Theresultsshowthatcontactangleandhardnessarechangedbyfillingn-HAandgammairradiation.Frictioncoefficientandwearrateunderdeionizedwaterlubricationarereducedbyfillingn-HA.Whilefrictioncoefficientisincreasedandwearrateisreducedsignificantlybygammairradiation.Thewornsurfaceofunfilledmaterialismainlycharacterizedasadhesivewearandabrasivewear,andthatofn-HAfilledmaterialismainlycharacterizedasabrasivewear.Aftergammairradiation,thedegreesofadhesiveandabrasivewearforunfilledmaterialandabrasivewearofn-HAfilledmaterialaresignificantlyreduced.Unfilledandfilledmaterialsafterirradiationaremainlyshownasslightfatiguewear.TheresultsindicatethatUHMWPEandUHMWPE/n-HAirradiatedatthedoseof150kGycanbeusedasbearingmaterialsinartificialjointsforitsexcellentwearresistancecomparedtooriginalUHMWPE.
简介:UHMWPEcompositesreinforcedwithBovineBoneHydroxyapatite(BHA)indifferentcontentswerepreparedbyheatpressingformationmethod.AhipjointwearsimulatorwasusedtoinvestigatethebiotribologicalbehaviorofUHMWPE/BHAcompositeacetabularcupsagainstCoCrMoalloyfemoralheadsinbovinesynovialubricationat37±1℃.ItwasfoundthattheadditionofBHApowdertoUHMWPEcanimprovethehardnessandcreepmodulusofUHMWPE/BHAcomposites,anddecreasetheirwearratesunderbovinesynovialubrication.WhenthecontentofBHAfillerparticleswasupto30wt%,UHMWPE/BHAcompositesdemonstratedthewelldesignperformancesofthesurfaceandbiotribologicalproperties.Fatigue,ploughingandslightadhesivewearwerethemainwearmechanismsforUHMWPEanditscomposites.Inaddition,thesizesofwearparticlesbecamelargerwithanincreaseinBHApowderaddition.TheseresultssuggestthatBHAfillerisadesirablecomponenttoincreasethewearresistanceofUHMWPE/BHAcompositesforbiomedicalapplications.
简介:摘要:以超高分子量聚乙烯(UHMWPE)为基体,玄武岩纤维单向布为增强材料,制备了连续玄武岩纤维增强UHMWPE预浸带,将若干层预浸带采用模压工艺制备了复合材料板,研究了玄武岩纤维的含量对于复合材料力学性能、层间破坏强度、热性能的影响。结果表明,当玄武岩纤维质量分数为40%、50%、40%时,复合材料的拉伸强度、弯曲强度、维卡软化温度达到了最大值,分别为170.625MPa、67.431MPa、144.656℃,比纯UHMWPE分别提高了610.938%、461.925%、7.952%;当玄武岩纤维含量为40%时,层间剪切强度达到最大值17.178MPa;冲击强度随纤维含量的提高而不断增大;当纤维含量低于30%时,热变形温度也随着纤维的含量提高而不断增大。通过电镜观察复合材料界面,预浸带中的纤维获得了良好的浸渍,整体均匀性良好。
简介:摘 要:超高分子量聚乙烯纤维与芳纶纤维、碳纤维并称世界三大高科技纤维,具有高强高模、耐酸碱、耐磨等特点。目前,湿法纺丝是国内工业化制备超高分子量聚乙烯(UHMWPE)纤维常用的方法,通常来说该方法有前、后纺之分,其前纺主要步骤是将UHMWPE粉料溶于溶剂中制成极稀溶液,再通过高长径比的螺杆挤出机挤出喷丝,进入凝固浴形成冻胶纤维。然而,这一过程中需要大量溶剂,目前工业化纺丝路线使用最多的溶剂是工业白油,其主要成分是饱和的环烷烃以及长链烷烃,但工业白油根据运动粘度不同分多种型号,作为UHMWPE纤维纺丝用白油,其粘度必须适中,以确保溶液的均匀性和稳定性。如果白油的粘度过高,可能会导致溶液过于黏稠,不利于纺丝,而粘度过低则可能导致溶液稳定性差,容易发生纺丝故障,当今工业生产中常用作UHMWPE生产的工业白油型号为46号及68号。本文主要对46号及68号白油对UHMWPE纤维纺丝性能影响作以下研究: