简介:Depositionoftwo-dimensional(2D)MoS2materialsonthetaperedfiberallowsvariousphotonicapplicationsincludingsaturableabsorbersandfour-wavemixing.Ethanolcatalyticdeposition(ECD)ofMoS2ontheopticaltaperedfiberwasproposedanddemonstratedinthiswork.Differentfromtheconventionalopticaldrivendepositionusingwaterororganicsolvent,theECDmethodutilizedthehighvolatilityoftheethanolsolvent,whichsignificantlyincreasedthemovementspeedoftheMoS2nanosheetsandthusboostedthedepositionrateandreducedtheminimumpowerthresholdtodrivethedeposition.WebelievetheECDmethodshouldbeabletobeappliedtoothersimilar2Dmaterialssuchasothertypesoftransitionmetalchalcogenides.
简介:Probingtheopticalpropertiesofmolybdenumdisulfide(MoS2)isvitaltoitsapplicationinplasmon-enhancedspectroscopy,catalysts,sensing,andoptoelectronicdevices.Inthispaper,wetheoreticallystudiedtheRamanandfluorescencepropertiesofmonolayerMoS2usingtip-enhancedspectroscopy(TES).Inthestrong-couplingTESsystem,theRamanandfluorescenceenhancementfactorscanbeturnedtoashighas4.5×108and3.3×103,respectively,byoptimizingthetip–MoS2-filmdistance.OurtheoreticalresultsnotonlyhelptodeeplyunderstandtheTESpropertiesofmonolayerMoS2,butalsoprovidebetterguidanceontheapplicationsofthenoveltwo-dimensionalmaterial.
简介:摘要:二硫化钼(MoS2)因具有独特的层状结构以及较高的本征催化活性,被认为是可替代贵金属催化剂的材料之一。但是,2H-MoS2表现为半导体特性,其催化性能受到其导电能力及活性位点数目的制约。因此,本文通过Li离子插层化学剥离法对块状2H相MoS2进行改性,制备出了尺寸为几到几十纳米的双相(1T相与2H相)MoS2纳米片,并系统评价了改性后催化剂的析氢活性与稳定性。相比于块体MoS2,MoS2纳米片表现出更佳的析氢(HER)催化性能,在电流密度为10mAcm2下的过电位较前者降低了170 mV,这主要归因于1T-MoS2能够暴露更多的活性位点,且1T-MoS2的存在促使催化剂的导电性增加。
简介:Amolybdenumdisulfide(MoS2)saturableabsorberwasfabricatedbythermallydecomposingtheammoniumthiomolybdate.ByusingtheMoS2absorber,acompactdiode-pumpedpassivelyQ-switchedTm:GdVO4laserhasbeendemonstrated.AstableQ-switchedlaserwithrepetitionratesfrom25.58to48.09kHzwasachieved.Maximumaverageoutputpowerwas100mWwiththeshortestpulsedurationof0.8μs.Maximumpulseenergyis2.08μJatcenterof1902nm.
简介:Two-dimensionalmaterialsaregeneratinggreatinterestduetotheiruniqueelectricalandopticalproperties.Inparticular,transitionmetaldichalcogenidessuchasmolybdenumdisulfide(MoS2)areattractivematerialsduetotheexistenceofadirectbandgapinthemonolayerlimitthatcanbeusedtoenhancenonlinearopticalphenomena,suchasRamanspectroscopy.Here,wehaveinvestigatedfour-wavemixingprocessesinbulkMoS2usingamultiplexcoherentanti-StokesRamanspectroscopysetup.Theobservedfour-wavemixingsignalhasaresonanceatapproximately680nm,correspondingtotheenergyoftheAexcitonictransitionofMoS2.Thisresonancecanbeattributedtotheincreasedthird-ordernonlinearsusceptibilityatwavelengthsneartheexcitonictransition.ThisphenomenoncouldopenthepathtousingMoS2asasubstrateforenhancingfour-wavemixingprocessessuchascoherentanti-StokesRamanspectroscopy.
简介:摘要:MoS2由于独特的理化性质作为光催化剂具有优良的催化活性,近年来,诸多学者将MoS2应用于光催化杀菌中,并取得良好的成果。本文对近年来MoS2在光催化杀菌中的研究进展进行了综述,并展望了其研究前景和方向。
简介:Liquid-phase-exfoliationtechnologywasutilizedtopreparelayeredMoS2,WS2,andMoSe2nanosheetsincyclohexylpyrrolidone.Thenonlinearopticalresponseofthesenanosheetsindispersionswasinvestigatedbyobservingspatialself-phasemodulation(SSPM)usinga488nmcontinuouswavelaserbeam.ThediffractionringpatternsofSSPMwerefoundtobedistortedalongtheverticaldirectionrightafterthelasertraversingthenanosheetdispersions.Thenonlinearrefractiveindexofthethreetransitionmetaldichalcogenidesdispersionsn2wasmeasuredtobe10-7cm2W-1,andthethird-ordernonlinearsusceptibilityχ(3)10-9esu.TherelativechangeofeffectivenonlinearrefractiveindexΔn2e∕n(2e)oftheMoS2,WS2,andMoSe2dispersionscanbemodulated0.012–0.240,0.029–0.154,and0.091–0.304,respectively,bychangingtheincidentintensities.Ourexperimentalresultsimplynovelpotentialapplicationoftwo-dimensionaltransitionmetaldichalcogenidesinnonlinearphasemodulationdevices.
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简介:ThisworkismainlytostudytheeffectofheavyionirradiationonthedamageofsinglelayerMoS2.ThenumberoflayersofMoS2preparedbyCVD(chemicalvapordeposition)methodwasdeterminedbyopticalmicroscopyandRamanspectroscopy.ThemonolayerMoS2preparedbyCVDunderhighenergy209BiionirradiationwasanalyzedbyRamananalysisandAFMobservation.AndtheresultsarecomparedandanalyzedbeforeandafterthebeamirradiationofsinglelayerMoS2preparedbymechanicalstrippingmethod.
简介:对磨损的液压泵铜舍金轴套采用Cu/MoS2复合刷镀修复。其刷镀工艺流程为:清洗→检测→保护非镀面→刷镀前处理→刷镀底层(碱性Cu)→刷镀工作层(Cu/MoS2复合镀层)。实践证明:采用铜基MoS2复合刷镀工艺,修复已磨损的液压齿轮泵铜合金轴套,具有较好的耐磨减摩性能。
简介:AtomicallythinMoS2filmshaveattractedsignificantattentionduetoexcellentelectricalandopticalproperties.Thedevelopmentofdeviceapplicationsdemandstheproductionoflarge-areathinfilmwhichisstillanobstacle.Inthisworkwedevelopedafacilemethodtodirectlygrowlarge-areaMoS2thinfilmonSiO2substrateviaambientpressurechemicalvapordepositionmethod.Thecharacterizationsbyspectroscopyandelectronmicroscopyrevealthattheas-grownMoS2filmismainlybilayerandtrilayerwithhighquality.Back-gatefield-effecttransistorbasedonsuchMoS2thinfilmshowscarriermobilityupto3.4cm2V-1s-1andon/offratioof105.Thelarge-areaatomicallythinMoS2preparedinthisworkhasthepotentialforwideoptoelectronicandphotonicdeviceapplications.
简介:Two-dimensional(2D)materialshaveattractedgreatresearchinterestsduetotheiruniqueproperties.2DMoS2,unlikeitsbulkformwhichwidelyusedassolidlubricantandcatalyst,isofbrilliantapplicationprospectinnanoelectronicsandoptoelectrnics.Theelectronicdevicesworkinkindsofradiationenvironment.Toevaluatetheionradiationeffectsonmaterialpropertiesandstabilityofdevice,theswiftheavyionradiationeffectonsingle-layerMoS2wasstudiedinthiswork[1??2].
简介:使用扫描电镜观察和分析了滚压不锈钢钢管的成型模具的表面磨损特性和形貌,分析了粘着磨损的形成机理,研究并制备了电刷镀Ni—w(D).MoS2复合镀层修复了已磨损的模具.结果表明,镀层明显改善了模具表面的抗粘着磨损性能,使模具的使用寿命明显提高,并取得了良好的经济效益.
简介:Thecounterelectrode(CE)prominenceindye-sensitizedsolarcells(DSSCs)isundisputedwithresearchgearedtowardsreplacementofPtwithviablesubstituteswithexceptionalconductivityandcatalyticactivity.Herein,wereportthereplaceableCEwithbetterperformancethanthatofPt-basedelectrode.ThechemistrybetweenthegrapheneoxideandicetemplatesleadstocellularformationofreducedgrapheneoxidethatachievesgreaterconductivitytotheCE.Thesimultaneousgrowthofactiveedge-orientedMoS2ontheCEthroughCVDpossesseshighreflectivity.HighreflectiveMoS2trendstoincreasetheelectroactivitybyabsorbingmorephotonsfromthesourcetodyemolecules.Thus,thesynergisticeffectoftwomaterialswasfoundtoshowcasebetterphotovoltaicperformanceof7.6%against7.3%fortraditionalplatinumCE.