简介：TheeffectoffrequencyandsampleshapeonfatiguebehaviorsofDZ125superalloyaresystematicallystudied.Theresultsshowthatfatiguefracturestilloccursabovethecycleof10~8fortestscarriedoutatthefrequencyoff=20kHzandstressratioR=-1,sothetraditionalfatiguelimitatcycleof10~7isnotappropriateforfatiguedesign.Fatiguefracturesurfacesareperpendiculartostressaxisforcylindricalandplatespecimens,andthefatiguecracksoriginatefromtheextrasurfaceofthespecimens.Fatiguecrackisapttopropagatefromcuttingdirectiontoforwarddirection,whichoccursmainlyinthesecondpropagationstageathigherstressamplitude.ThereisanobviousfrequencyeffectforDZ125superalloy.Thehigherthetestfrequencyis,themoreserioustheeffectoffrequencyonfatiguebehaviorsofthealloy.Afterthefrequencycorrection,theultra-highcyclefatigueS-NcurvewellcoincidewiththetraditionalfatigueS-Ncurve.

简介：以2-醛基吡啶和1，2-二（对氨基苯氧基）乙烷进行缩合得到Schiff碱配体L，然后与AgSbF6进行配位反应，得到了席夫碱配合物[Ag（L）SbF6]n，用元素分析、FT-IR和X-射线单晶衍射进行了表征．结果表明，配合物属于单斜晶系，P21／n空间群，每个Ag（I）的配位环境均为扭曲四面体，每个配体L通过其两端的2个N原子同2个金属离子配位桥联形成一维螺旋链结构．

简介：Shortpeptidesbasedonthetripeptides,Leu-Arg-ProandLeu-Lys-Pro,weresynthesizedbymicrowaveassistedsolid-phasesynthesismethod,inordertomakeasearchforpotentialinhibitorsforangiotensinI-convertingenzyme(ACE)withminimumsideeffectsinthetreatmentofhypertension.OnepeptidewiththesequenceLeu-Arg-Pro-Phe-PheshowsthestrongestinhibitiontowardsACEwithanIC50valueof0.26μmol/Linvitro.Thestudyofstructure-activityrelationshipshowsthattheintroductionofabulkygroupintotheN-terminalofthisseriesofinhibitorsmayenlargesterichindrance,resultinginthepoorinhibitoryactivitytowardsACE.TheinhibitoryactivitydecreasedinturnwhenL-Pro,D-ProorAc6cwasattheC-terminalrespectively.ThebindinginteractionbetweeneachoftheseinhibitorsandtesticularACE(tACE)wasperformedbymoleculardocking.TheresultssuggestthatLeu-Arg-Pro-Phe-PhemainlyoccupiedtheS1subsiteoftACE,andmadecontactwithtACEviasevenH-bonds.ItappearedthatthesiteonthepeptidethatboundwithtACEwasinfluencedbytheconfigurationoftheaminoacid,LorD-form,attheC-terminalofthepeptide.

简介：2011年'高教社杯'全国大学生数学建模竞赛A题'城市表层土壤重金属污染分析'提出了一个从稀疏的污染元素抽样数据估测污染源的问题。本文通过数学建模给出了一个可行的方法。首先,通过建立重金属载体的可压缩流体欧拉连续性方程,并结合问题实际,得到了简化的可压缩流体欧拉连续性方程,建立了沿特征线估测孤立污染源的数学模型;其次,利用稀疏的检测值建立了更切合实际的修正的Shepard插值,设计了沿流线估测可孤立区域污染源的算法;最后,基于所提出的模型和算法,应用赛题数据给出了重金属铜的3个孤立污染源。

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简介：利用火花源直读光谱对阳极铜进行直接快速分析，通过改进原分析程序，增加了氧元素分析通道。可快速准确测定阳礼极铜中19种杂质元素，并计算出主铜含量，RSD为0．01％～4．00％，满足了生产控制要求，已应用于阳极铜的日常检测工作中。