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71 个结果
  • 简介:激光冲击强化是一种新型表面处理技术,利用高功率激光束冲击金属零件表面,在零件表面形成较大的残余压应力,可有效改善零件的疲劳性能。以发动机1Cr11Ni2W2MoV叶片为研究对象,对其进行了激光冲击强化处理,研究强化处理对材料的微观组织和疲劳性能的影响。研究结果表明:相比未处理试样,激光冲击强化在1Cr11Ni2W2MoV叶片材料表层形成较大的残余压应力,表层晶粒更为细化,叶片的疲劳寿命提高1.7倍。

  • 标签: 1Cr11Ni2W2MoV 叶片 激光冲击强化
  • 简介:针对激光直接沉积修复的1Cr15Ni4Mo3N钢零件在磁粉检测时出现的磁痕现象,采用接触通电、湿磁粉连续法,对设计的试样进行磁粉检测,确定磁痕显示位置;利用光学显微镜对磁痕显示处形貌及修复接头和组织进行观察和研究,分析磁痕的性质和形成原因。研究发现:激光直接沉积修复1Cr15Ni4Mo3N钢在磁粉检测过程中与修复区外轮廓完全重合的磁痕显示是伪磁痕显示,主要是由修复区与基体中奥氏体含量的差异造成的。

  • 标签: 激光直接沉积 激光修复 1Cr15Ni4Mo3N钢 磁粉检测 磁痕
  • 简介:MechanicallyactivatedW-Cupowdersweresinteredbyasparkplasmasinteringsystem(SPS)inordertodevelopanewprocessandimprovethepropertiesofthealloy.Propertiessuchasdensityandhardnessweremeasured.ThemicrostructuresofthesinteredW-CualloysampleswereobservedbySEM(scanningelectronmicroscope).Theresultsshowthatsparkplasmasinteringcanobviouslylowerthesinteringtemperatureandincreasethedensityofthealloy.Thisprocesscanalsoimprovethehardnessofthealloy.SPSisaneffectivemethodtoobtainW-Cupowderswithhighdensityandsuperiorphysicalproperties.

  • 标签: 钨铜合金 粉末冶金 机械活化 火花等离子体烧结
  • 简介:1Cr15Ni4Mo3N沉淀硬化不锈钢螺栓零件在制造工序磁粉检测时,发现螺栓表面有一条疑似裂纹状线性磁痕显示,后采用荧光渗透检测方法进行辅助检测,原磁痕显示处未见异常荧光显示。结合金相试验分析发现,螺栓原材料内呈带状分布的残余奥氏体,破坏了基体组织和材料磁性的连续性导致出现磁痕显示。研究为该材料在零件制造中磁粉检测的磁痕判定提供了依据。

  • 标签: 沉淀硬化不锈钢 磁粉检测 残余奥氏体 偏聚
  • 简介:CurieTemperatureofAmorphousFeSiBandFeWSiBAloysWangLingling,ZhaoLihua,HuWangyu(王玲玲)(赵立华)(胡望宇))DepartmentofPhysics,HunanUn...

  • 标签: CURIE TEMPERATURE FeSiB and FeWSiB ALLOYS
  • 简介:世界经济可能呈现“L”走势,在见底后出现较长时间的低迷;中国经济可能出现“W”的走势,自第二季度开始反弹,到明年第一季度再度回落。

  • 标签: 中国经济 世界经济 曹远征 “L”走势
  • 简介:SiC/Si<潜水艇class=“a-plus-plus”>3N<潜水艇class=“a-plus-plus”>4合成是用自我繁殖的高温度的燃烧合成-Si3N<潜水艇class=“a-plus-plus”>4粉末和适当数量原文如此搽粉。两个都,sintering添加剂,系统被使用,它是YAN(Y2O3艾尔2O3AlN)并且YN(Y2O3AlN)。影响在SiC/Si的sintering行为上原文如此满意<潜水艇class=“a-plus-plus”>3N<潜水艇class=“a-plus-plus”>4合成被调查。结果证明有二个sintering添加剂系统的样品的密度,收缩,弯曲力量,坚硬,和破裂坚韧随内容的增加增加第一原文如此然后甚至当原文如此内容不断地增加时,减少。样品的重量损失的趋势是相反的。有最好的机械性质的样品原文如此满意在二个系统是不同的。为YAN系统,当原文如此内容到达10时,样品的最好的机械性质被获得?%,当至于YN系统它是5时?%。YN样品的性质比YAN样品优异。J阶段(2Y2O3吠敨爠畯整漠?灡汰楹杮氠睯瀠敲獳牵?景???慐漠?桴?獡搭獩牰灯牯楴湯瑡摥朠敲湥挠浯慰瑣搠牵湩?桴?敤潳灲楴湯爠'啼礃A慮楴湯瀠潲散獳椠?楳畴栠瑯搠晥牯慭楴湯椠??灳牡?汰獡慭猠湩整楲杮?偓?猠獹整?慣?扯慴湩挠浯汰瑥汥?敲潣扭湩摥丠??洠条敮?楷桴朠潯?湡獩瑯潲祰愠摮洠条敮楴?牰灯牥楴獥?桔?慭楸畭?慭湧瑥捩瀠潲数瑲敩??????汣獡?愢瀭畬?汰獵?慭?猯'T?????鮪徬鞪??极脿???醰鑛??鴿鎘銳????�

  • 标签: 复合材料性能 烧结行为 碳化硅粉 添加剂系统 弯曲强度 断裂韧性
  • 简介:ThesubmicronpowdermixturesofTiC-TiN-WC-Mo-C-Nisinteredat1400℃orbelowinvacuumwerestudiedbyX-raydiffraction(XRD),scanningelectronmicroscopy(SEM)andtransmissionelectronmicroscopy(TEM)analyses.TheresultsshowedthatMo2Cformedat800℃orbelow.BothWCandMo2Cdisappearedat1200℃,andTiNdisappearedat1250℃.Inaddition,thevariationsoflatticeconstantsofthetitaniumcarbonitrideandnickelbinderphasewithsinteringtemperaturewereexperimentallyobtained,andthereasonwasanalyzed.

  • 标签: SUBMICRON CERMET PHASE SINTERING
  • 简介:散热问题已成为电子设计者面前的最大挑战之一,研究开发导热性好并且与铜箔(铜线路)间有较好的粘结强度和刚度的绝缘层材料对HDI电路板的应用具有重要意义。随着2008年欧盟RoHS指令的逐步开始实施,现有电子元器件含溴阻燃体系逐渐禁用,因此无卤2W导热率导热膜开发意义重大。

  • 标签: 高密度互连(HDI) 导热率 导热膜
  • 简介:Usingdensityfunctionalmethods,somepropertieswerestudiedsuchastheenergiesandcompositionsoffrontiermolecularorbitalsandtheatomiccharges,whicharerelatedtothereactivebehaviorofthioureascontainingdifferentN-substituentgroupings.ThecalculationresultsindicatethattheN-substituentgroupingshavesignificanteffectontheflotationperformanceofthioureacollectors.Theorderofelectron-donatingabilityisN-propyl-N'-benzyl-thiourea(PBZYTU)>N-propyl-N'-ethyl-thiourea(PETU)>N-propyl-N'-allyl-thiourea(PALTU)>>N-propyl-N'-acetyl-thiourea(PACTU)>N-propyl-N'-ethoxycarbonyl-thiourea(PECTU)>N-propyl-N'-benzoyl-thiourea(PBZOYTU),andtheorderoffeedback-electron-acceptingabilityisPBZOYTU>PACTU>PECTU>>PALTU>PETU>PBZYTU.ThisimpliesthatPBZOYTU,PACTUorPECTUcanreactwithcopperatomshaving(t2g)6(eg)3Cu(II)ort6e4Cu(I)configurationonthesurfacesofcoppersulfidemineralsthroughnormalcovalentbondandbackdonationcovalentbond,andexhibitexcellentlycollectingperformanceforcoppersulfideminerals.Theseareconsistentwiththeexperimentaldatareportedintheliteratures.

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  • 简介:GaxIn1-xAs1-ySbyalloyshavebeengrownbyatmosphericpressureMOCVDonn-GaSb(Te-doped)substrate.Thesohdcompositionwasdeterminedbyusingelectronmicroprobe.ThealloysofGalnAsSbwithcompositioninmiscibilitygapweresuccessfullygrown.TheopticalpropertiesofGaxIn1-xAs1-ySbylaverswerecharacterizedbythephotoluminescenceandtheinfraredabsorption.Thespectralresponsesofp+-GaInAsSb/p-GaxIn1-xAs1-ySby/n-GaSbdetectorsshowedwavelengthcutoffat2.4μmanddetectivity-D*=5×108cmHz1/2/Watroomtemperature.

  • 标签: MOCVD GaxIn+(1-x)As1-ySby Photoluminescence INFRARED absorption INFRARED
  • 简介:氮(N)和磷(P)共同做锐钛矿TiO2nanosheets被与外国先锋做的高温度的P跟随的低温度的自我做的N-TiO2认识到。做过程的P能维持好TiO2nanosheets形态学与,这被发现暴露{001}方面。掺杂物的化学状态显示N和P原子在TiO2格子在O地点上代替O。与纯TiO2和做N的TiO2,N-P相比,共同做的TiO2nanosheets在可见轻政体展出更强壮的光吸收和染料分子的更高的降级率。提高的photocatalytic性质被归因于二个因素。一方面,N-P共同做能有效地从3.20~2.48减少TiO2的乐队差距?eV,在可见的光导致吸收的改进政体。在另一方面,存在暴露{001}TiO2nanosheets的方面能在反应导致photogenerated电子和洞的有效分离。

  • 标签: TIO2纳米 光催化性能 共掺杂 锐钛矿型 染料分子 光生电子
  • 简介:Solventextractionofpalladium(Ⅱ)fromhydrochloricacidsolutionwith2-n-octyl-4-isothiazolin-3-one(OIT)/cyclohexanewasstudied.Effectsofdifferentparametersonextractionefficiencywereevaluated.99.96%and98.26%palladium(Ⅱ)couldbeeffectivelyextractedwith0.018mol·L-1OIT/cyclohexaneof0.1and4.0mol·L-1HClmedium,respectively.Nonpolarsolventandlowaciditycouldimprovetheextractingefficiency,andsuccessfullystrippalladium(Ⅱ)fromtheloadedorganicphasewasachievedwith0.5mol·L-1(NH2)2CSsolution.ItwasproposedthattheextractionofPdcomplexesfromHClmediumproceededthroughtheionassociationmechanismbyslopemethod,NMRandFT-IRspectra.

  • 标签: 溶液萃取 盐酸溶液 正辛基 噻唑啉 萃取剂
  • 简介:LayeredcathodematerialLiCo1/3Ni1/3Mn1/3O2wassynthesizedbyPechiniprocess,andinvestigatedusingX-raydiffraction(XRD),scanningelectronmicroscopy(SEM)andgalvanostaticcharge/dischargecycling.Thesampleiswell-crystallizedandhasaphase-purea-NaFeO2structure.Theparticlesizesareuniform,anddistributedintherangeof20-200nm.TheinitialdischargecapacityoftheLi/LiCo1/3Ni1/3Mn1/3O2cellwasabout149mAh·g-1whenitwascycledatavoltagerangeof4.5-2.3Vwithaspecificcurrentof0.25mA.Theresultisbetterincomparisonwithsolid-statesolutionmethod.Thesyntheticprocedurewasdiscussed.Threemajorreactions:chelation,esterification,andpolymerizationsuccessivelyoccurred.

  • 标签: LAYERED CATHODE material LiCo1/3Ni1/3Mn1/3O2 PECHINI method
  • 简介:双面挠性覆铜板及其制作方法/CN101420820/申请人广东生益科技股份有限公司本发明涉及一种双面挠性覆铜板及其制作方法,该双面挠性覆铜板包括一单面覆铜板、涂布于该单面覆铜板上的胶粘剂层、以及压覆于该胶粘剂层上的另一铜箔或另一单面挠性覆铜板,所述单面覆铜板包括一铜箔以及涂布于铜箔上的聚酰亚胺层,所述聚酰亚胺层与胶粘剂层相邻设置。

  • 标签: 挠性覆铜板 专利 文摘 聚酰亚胺 胶粘剂 单面
  • 简介:EmployingLi2CO3,NiO,Co3O4,andMnCO3powdersasstartingmaterials,Li[Ni1/3Co1/3Mn1/3]O2wassynthesizedbysolid-statereactionmethod.Variousgrindingaidswereappliedduringmillinginordertooptimizethesynthesisprocess.Aftersuccessiveheattreatmentsat650and950℃,thepreparedpowderswerecharacterizedbyX-raydiffraction(XRD)analysis,scanningelectronmicroscopy,andtransmissionelectronmicroscopy.Thepowderspreparedbyaddingsalt(NaCl)asgrindingaidexhibitaclearR3mlayerstructure.ThepowdersbyothergrindingaidslikeheptaneshowsomeimpuritypeaksintheXRDpattern.Theformerpowdersshowauniformparticlesizedistributionoflessthan1μmaveragesizewhilethelattershowsawidedistributionrangingfrom1to10μm.EnergydispersiveX-ray(EDX)analysissshowthattheratioofNi,Co,andMncontentinthepowderisapproximately1/3,1/3,and1/3,respecively.TheEDXdataindicatenoincorporationofsodiumorchlorineintothepowders.Charge-dischargetestsgaveaninitialdischargecapacityof160mAh·g-1forthepowderswithNaCladditionwhile70mAh·g-1forthepowderswithheptane.

  • 标签: LITHIUM ion battery CATHODE materials LAYERED
  • 简介:前言:环境中的铅作为一种污染物,对人身体有重大危害,在全世界范围内不存在争议。现在ROHS法案即将正式实施,这标志着无铅化时代已经来临。日本是世界工业强国,为了提高竞争门槛,领先于竞争对手,现在已经制定了无卤覆铜板标准。日本企业积极行动,在国内全部采用无卤材料来生产覆铜板。本文介绍了一种同时满足无卤阻燃和适应无铅焊接的FR-1的研制工作。

  • 标签: 无卤素 世界范围 竞争对手 日本企业 无卤材料 研制工作
  • 简介:PolycrystallinesamplesofLa12x(Sr12yAgy)xMnO3(y=0.0,0.2,0.4,0.6,1.0)werepreparedbythesolid-statereactionmethod.ThetemperaturestabilityofmagnetoresistanceandmagnetoresistanceenhancementinLa1-x(Sr1-yAgy)xMnO3systemwithbothunivalentandbivalentelementsdopedatAsiteandwithunchangedvalueofMn3+/Mn4+ratiowereexploredthroughthemeasurementsofX-raydiffractionpatterns,magnetiza-tion-temperature(M-T)curves,resistivity-temperature(q-T)curvesandmagnetoresistance-temperature(MR-T)curves.Theresultsareasfollows:therearetwopeaksintheq-TcurvesofthesampleswithAgdoping,oneiscausedbyresistancechangeduringtheparamagnetism-ferromagnetismtransition,andtheotherisfromboundary-dependentscatteringofconductionelectronsontheboundariesofgrains.ThepeakvalueofMRincreaseswithincreasingAgdopingcontent,anditincreasesfrom8.2%fory=0.2to29.6%fory=1.0underthemagneticfieldofB=0.8T;MRremainsaconstantof12%inthetemperaturerangeof218-168Kforthesamplewithy=1.0,andthetemperaturestabilityofMRisinfavorofthepracticalapplicationofMR.

  • 标签: 温度稳定性 MR 系统 温度曲线 磁阻 AG掺杂
  • 简介:TheintermetalliccompoundZr1-xTixCowaspreparedanditssuitabilityforhydrogenstoragewasinvestigated.ThealloysobtainedbymagneticlevitationmeltingwiththecompositionofZr1-xTixCo(x=0,0.1,0.2and0.3,at.%)showsinglecubicphasebyX-raydiffraction.Asingleslopingplateauwasobservedoneachisothermal,andpressure-composition-temperature(PCT)measurementresultsshowthattheequilibriumhydrogendesorptionpressureofZr1-xTixCoalloyincreaseswithincreasingTicontent.Thedesorptiontemperaturesforsupplying100kPahydrogenareabout665,642,621and614KforZrCo,Zr0.9Ti0.1Co,Zr0.8Ti0.2CoandZr0.7Ti0.3Coalloy,respectively.RepeatedhydrogenabsorptionanddesorptioncyclesdonotgenerateseparatedZrCo,TiCoandZrH2phases,indicatingthatalloyshavegoodthermalandhydrogenstabilization.

  • 标签: HYDROGEN storage alloy ZrCo INTERMETALLIC COMPOUND
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