学科分类
/ 1
7 个结果
  • 简介:1-Ethoxycarbonylalkyldiphenylpolystyrylphosphoniumtriflatescanbeeasilypreparedbyquaternizingdiphenylpolystyrylphosphinewithethyl2-trifloxyalkanoates;basetreatmentofthesepolymer-supportedphosphoniumtriflatesaffords1-ethoxycarbonylalkylidenephosphoraneswhicharestableandundergosatisfactoryWittigreactions.

  • 标签: 制备 三苯基磷化氢 1-乙氧甲酰次烷基二苯基多苯乙烯基正膦
  • 简介:PolymericGrignardReagent(PGR)basedonthechloromethylatedpoly(ST-co-DVB)resinhasbeenpreparedbymeansofanthracene-magnesiumcomplexinTHF(Anth-Mg-THF),andpolymermatrixwithlongpolymethylenespacerwassynthesizedviathecouplingreactionbetweenPGRandα,ω-dibromoalkanes.Basedonthestudiesoffactorsaffectingthecoupling,suchascatalyst,reactiontime,thelengthofspaceretc.,thispaperofferstheoptimalreactionconditionsandthreetypicalexperimentprocedures.ThemechanismfortheformationandcouplingreactionofPGRarealsodiscussed.

  • 标签: GRIGNARD REAGENT Polymer SUPPORTED Anthracene Coupling
  • 简介:Anovelbeadfromofploymerofhighsorptioncapacityforureawereobtainedbythereactionofglutaricdialdehydewithchitosandispersedinaceticacidsolution.Thesorptioncapacityreached-82.0mg/gsorbentat37℃andpH7.4Theconcentrationofureainthebuffersolutionwas1300mg/l.Thesorptionofureawasrelatedtothedegreeofcrosslinkingofthesorbent,concentrationofurea,ionicstrengthandtemperature.

  • 标签: 合成 交联壳聚糖 尿素分离
  • 简介:新奇结合的聚合物,poly(1),在主要的链包含thiourea一半经由联合反应的铃木被综合。亚铜的离子的增加熄灭荧光(1)而荧光在另外的金属离子的增加之上稍微变化,poly展出荧光灯向Cu+察觉到能力的几乎转弯。当氢过氧化物被加到poly包含的答案(1)和Cu+,Cu时,+被氧化进导致荧光恢复的Cu2+,。H2葡萄糖oxidase(上帝)免除葡萄糖氧化的O2也恢复了荧光poly(1)/Cu+答案。结果显示(1)poly,/Cu+答案能为氢过氧化物和葡萄糖用作一个察觉到的平台。

  • 标签: 荧光化学传感器 共轭聚合物 过氧化氢 铜离子 葡萄糖 硫脲