摘要
PolymericGrignardReagent(PGR)basedonthechloromethylatedpoly(ST-co-DVB)resinhasbeenpreparedbymeansofanthracene-magnesiumcomplexinTHF(Anth-Mg-THF),andpolymermatrixwithlongpolymethylenespacerwassynthesizedviathecouplingreactionbetweenPGRandα,ω-dibromoalkanes.Basedonthestudiesoffactorsaffectingthecoupling,suchascatalyst,reactiontime,thelengthofspaceretc.,thispaperofferstheoptimalreactionconditionsandthreetypicalexperimentprocedures.ThemechanismfortheformationandcouplingreactionofPGRarealsodiscussed.
出版日期
1995年01月11日（中国期刊网平台首次上网日期，不代表论文的发表时间）
