学科分类
/ 8
156 个结果
  • 简介:到杀虫药剂的危险性被从南部的Karnataka的不同地点收集棕色的planthopper的地人口调查,印度(Gangavati,Kathalagere,Kollegala,Soraba和Mandya)。所有地人口在他们的危险性不同到杀虫药剂。一般来说,Soraba和Mandya人口更产生与Gangavati和Kathalagere人口相比的杀虫药剂。抵抗比率在人口viz之中极大地变化了,chlorpyriphos(到16.82褶层的1.13-),imidacloprid(到13.50褶层的0.53-),acephate(到5.32褶层的1.34-),fipronil(到4.06褶层的1.13-),thiamethoxam(到2.19褶层的1.01-),clothianidin(到4.86褶层的1.92-),dinotefuran(到2.22褶层的0.82-),buprofezin(到5.43褶层的1.06-)和carbofuran(到2.17褶层的0.41-)。从Gangavati,Kathalagere和Kollegala的人口展出了更高的抵抗到一些旧杀虫药剂和低抵抗到新分子。

  • 标签: 田间种群 褐飞虱 敏感性 纳塔 印度 电阻率差异
  • 简介:Anewdi-functionadsorbent(JN-3)waspreparedbysulfhydrylmodified.ComparingwithAmberliteXAD-4andNDA-150,theequilibriumadsorptionforphenolontheJN-3fromaqueoussolutionswastested,perfectadsorptioncapacitywasshown.Pb2+canbealsoremovedbyJN-3becauseofthechelateinteractionbetweensulfhydrylgroupsandmetalions.Thisadsorbentcouldbeusedinremovalofcombinepollutantssuchasphenoliccompoundsandheavymetalionsfromwastestreams.

  • 标签: 氢硫基 化学元素 表面现象 石碳酸 吸附实验
  • 简介:Twonew15-memhoredfimctionalizedmacrocycles,dioxo-polyazacydoalkaneswiththreependantacetatogroups,havebeensynthesizedbythecondensationreactionofDTPAdianhy-dride(DTPA=diethylenetrlamlnepentaaceticacid)with1,2-di-amlnopropane,(15-DTPA-1,2-pn),or1,2-diaminocydohex-ane,(15-DTPA-1,2-cy).Theirlanthanidecomplexes[Ln(15-DTPA-1,2-pn)(H2O)]2[Ln=Eu(1),Gd(2)]and[Ln(15-DTPA-1,2-cy)(H2O)]2[Ln=Eu(3),Gd(4)]werealsopre-pared.SinglecrystalX-raydiffractionanalysesofcomplexes2and4showthattheyhavedimericstructuresinsolidstate;eachmetalionisnine-coordinatedinadistortedtricapped-trig-onalprism.Incomplex4,thecoexistenceoftwodiastereoiso-mericmoleculesinthecrystallatticewasobserved.

  • 标签: 合成 晶体结构 镧系配合物 大环配合物 X射线衍射分析 乙酰基团
  • 简介:Twonovelcyclotriphosphazenederivativescontaining6-(4-hydroxyphenyl)-2,2'-bipyridine(hopbp)sidegroups,N_3P_3(dobp)_2(hopbp)_2(1)andN_3P_3(dobp)(hopbp)_4(2)(dobp=2,2'-dioxybiphenyl),weresynthesizedandcharacterized.Thesecompoundsdisplaystrongfluorescentemissionbothinsolutionandinsolidstate.Theirabsorptionandemissionspectraaresensitivetoproton:theadditionofHBF4tothemethanolanddichloromethanesolution(9∶1,volumeratio)ofcompound1ledtoared-shiftfrom350to460nmfortheemissionspectrum,andtheprocesswasalsocharacterizedbyisosbesticpointsofabsorptionspectraat267,287and313nm.

  • 标签: 二嘧啶 合成 质子 光谱学
  • 简介:Theadsorptionbehaviorofionicgoldontochelatingfibercontainingamidoximegroupswasinvestigated.ThechelatingfiberpresentshighadsorptioncapacityforionicgoldAu^3+(upto626mg/g,whenthecontentofamidoximegroupreaches7.59mmol/g),andpossessestheabilitytoreducetheAu^3+intometallicgold,Intheredoxprocess,theamidoximegroupisoxidizedintocarboxylgroup.

  • 标签: 螯合纤维 三价金离子吸附行为 偕胺肟基团
  • 简介:Anovelsolubleπ-conjugatedpolymer,poly[(3-acetylpyrrole-2,5-diyl)p-(N,N-dimethylamino)azobenzylidene](PAPDMAABE),wassynthesizedbycondensationof3-acetylpyrrolewith4-aldehyde-4'-dimethylaminoazobenzene(ADMAA).ThechemicalstructureofPAPDMAABEwascharacterizedbyFouriertransforminfraredspectroscopy(FTIR),1H-NMR,andUV-Vis-NIRspectra.Transmissionelectronmicroscope(TEM)analysisforPAPDMAABEindicatesthatpartofPAPDMAABEisincrystalstate,duetotheshort-rangeorderofthepolymer.Thermogravimetricanalysis(TGA)curveshowsthatthepolymerhasgoodthermalstabilityanditsdecompositiontemperatureis248℃.TheopticalbandgapofPAPDMAABEobtainedfromtheopticalabsorptionspectrumisabout1.73eV.Theresonantthird-ordernonlinearopticalpropertyofPAPDMAABEat532nmwasstudiedusingdegeneratefour-wavemixing(DFWM)technique.Theresonantthird-ordernonlinearopticalsusceptibilityofthepolymerisabout7.48×10-8esu.

  • 标签: 聚乙烯 非线性光学性质 聚合体 化学结构
  • 简介:

  • 标签:
  • 简介:Slightlycrosslinkedmonodispersepoly(maleicanhydride-cyclohexylvinylether-divinylbenzene)(MA-CHVE-DVB)microsphereswerepreparedviaprecipitationpolymerizationwhileusing2,2-azobisisobutyronitrileasaninitiatorinamixtureofmethylethylketoneandn-heptanewithoutanystabilizer.Thenumber-averagediameteroftheresultantpoly(MA-CHVE-DVB)microspheresrangedfrom0.478to1.386μmwithapolydispersityindexof1.00to1.02thatdependedonthefeedratiosoftheMA/CHVE/DVBmonomers.Theintroductionofoneelectrondonormonomercyclohexylvinyletherstronglyaffectedtheyield,size,andmorphologyoftheseslightlycrosslinkedmicrospheres.Quinolinetypechelatingresinswereobtainedaftercombiningthepoly(MA-CHVE-DVB)with8-hydroxyquinoline;theadsorptionpropertiesofthesematerialsweremeasuredthroughtheirabilitytoremoveCu2+ionsfromwater.Thepoly(MA-CHVE-DVB)microsphereswithlowdegreesofcrosslinldngprovidedmoreeffectivefunctionalgroupsandthereforebetterionremovalcapabilities.Theseslightlycrosslinkedmicrospheresmayhaveapplicationsinwatertreatmentaswellasinsensinganddrugdelivery.

  • 标签: 二乙烯基苯 马来酸酐 乙烯基醚 沉淀聚合 微交联 环己基
  • 简介:Networkcrownetherpolymerwithpendantsulfidesidechaininthenetworkstructureunitshasbeensynthesizedviaring-openingcopolymerizationofβ-ethylthioethylglycidyletheranddiethyleneglycolbisglycidylether.Akindofactivecatalystsuitableforthisreactionwassuggested.Thetitlepolymerwasfoundtobeagoodligandforplatinouschloride,andtheplatinouscomplexcouldcatalyzethehydrosilylationofolefinswithtriethoxysilaneefficiently.

  • 标签: 聚合冠醚 硫化铂配合物 合成 氢化硅烷化催化剂
  • 简介:Objective:Theaiminthisstudywastoidentifytheallelicfrequenciesofthechemokine(SDF1-3'A)andchemokinereceptor(CCR5△32,CCR5m303andCCR2-64I)genesresistanttoHIV-1infectionand/ordiseaseprogressioninindigenousChinesepopulations.Methods:ByusingQIAampDNABloodMiniKit,thegenomicDNAsampleswerepurifiedfromwholeperipheralbloodofhealthyindividuals(n=2067)fromHan,Uygur,MongolianandTibetanethnicgroups,aswellasHanpatientsincludingHIV-1carriers(n=330),patientswithothersexuallytransmitteddiseases(STDs,n=259)andintravenousdrugusers(IVDUs,n=125).TheallelicpolymorphismswereidentifiedbymeansofPCRorPCR-RFLPanalyses.ThesequencesofrandomlyselectedamplifiedPCRproductswerefurtherconfirmedbydirectDNAsequencing.Results:Themutantfrequencieswereidentifiedtobe0%-3.48%forCCR5△32,0%forCCR5m303,19.15%-28.79%forCCR2-64and19.10%-28.73%forSDF1-3'Aalleles,respectively,inChinesehealthyindividualsfromfourethnicgroups.Ourfindingsindicatedtheallelicfrequenciesvaryamongthedifferentethnicgroups.Furthermore,theHIV-1carriers,STDcasesandIVDUs(allofHanethnicity)werefoundtohavetheallelicfrequenciesof0%-0.19%(CCR5A32),0%(CCR5m303),19.31%-20.45%(CCR2-64)and25.61%-26.83%(SDF1-3'A)withminorvariationsintheirfrequenciesbetweenthepatientsandhealthyHangroups.TherewasnoCCR5-m303mutationfoundinanysubjectinthisstudy.Conclusion:TheexaminedsubjectsoffourChineseethnicoriginsshowedlowerfrequenciesofCCR5A32andCCR5m303alleles,buthigherfrequenciesofmutantCCR264IandSDF1-3'Aallelescomparedtothoseidentifiedinnorthern-EuropeanandAmericanCaucasians.ThesignificanceofthedifferentfrequenciesandpolymorphismsoftheaboveallelesinChinesepopulationsneedstobefurtherexaminedinHIV-1/AIDSdiseases.

  • 标签: 爱滋病 AIDS 人体免疫缺损病毒1型 HIV-1 等位基因频率 基因多态性