简介:在Ce1-xDyx-ySryO2-δ体系中,研究了Dy和Se对总离子电导率的影响。在该体系中,使用麦芽糖和果胶作为有机前驱体,通过改性溶胶-凝胶工艺,在x=0.15,y=0.015,0.03和0.045的条件下,制备不同组分的导电体。采用X射线衍射谱的Rietveld拟合验证了导电体具有空间群Fm3m的立方结构。从SEM像可以看到具有明显晶界、相对均匀的晶粒。在150-500℃的温度范围和40Hz-1MHz的频率范围内,采用四探针交流阻抗法测量导电体的总离子电导率。与单掺杂的二氧化铈样品相比,Ce0.85Dy0.12Sr0.03O2-δ具有更高的电导率。
简介:HotcompressionbehaviorofTiC–Al2O3/AlcompositeswasstudiedusingtheGleeble-1500systematatemperaturerangeof300–550°Candatstrainraterangeof0.01–10.00s-1.TheassociatedstructuralchangeswerestudiedbyTEMobservations.Theresultsshowthatstressleveldecreaseswithdeformationtemperatureincreasingandstrainratedecreasing,whichcanberepresentedbyaZener–Hollomonparameterinanexponent-typeequationwithhotdeformationactivationenergyQof172.56kJ·mol-1.Dynamicrecoveryoccurseasilywhenstrainratesarelessthan10.00s-1.Dynamicrecrystallizationcanoccuratstrainrateof10.00s-1.
简介:NanocrystallineMg2Ni-typealloyswithnominalcompositionsofMg20Ni10–xCux(x=0,1,2,3,4,massfraction,%)weresynthesizedbyrapidquenchingtechnique.Themicrostructuresoftheas-castandquenchedalloyswerecharacterizedbyXRD,SEMandHRTEM.Theelectrochemicalhydrogenstorageperformancesweretestedbyanautomaticgalvanostaticsystem.ThehydridinganddehydridingkineticsofthealloysweremeasuredusinganautomaticallycontrolledSievertsapparatus.Theresultsshowthatalltheas-quenchedalloysholdthetypicalnanocrystallinestructureandtherapidquenchingdoesnotchangethemajorphaseMg2Ni.Therapidquenchingsignificantlyimprovestheelectrochemicalhydrogenstoragecapacityofthealloys,whereasitslightlyimpairsthecyclingstabilityofthealloys.Additionally,thehydrogenabsorptionanddesorptioncapacitiesofthealloyssignificantlyincreasewithrisingquenchingrate.
简介:这份报纸在极其细小的颗粒的WC-12%Co合金的磁性、机械的性质上处理codopedVC/Cr3C2和sintering温度的效果。结果证明在最佳的比例的做的VC/Cr3C2的synergistic行动提高坚硬和合金的横向的破裂力量(TRS),与更多的同类的微观结构。当合金是在1430点的sintered时?C并且与0.5%Cr3C2/0.2%VC,TRS到达3786MPa,坚硬是91.7HRA和比0.6m小的谷物尺寸。谷物生长上的数字分析在sintering过程期间证明在WC谷物边界并且Cr3C2溶解在公司上猛抛的两VC分阶段执行减少固体/液体的界面的精力,溶解和降水的过程极大地被延迟,WC谷物变粗被禁止。
简介:AZr-1.15wt%Cr-0.10wt%Fealloywasbeta-quenchedfrom1050℃toproduceasupersaturatedα′-phase,andthenheatedforvaryingtimesattemperaturesfrom650℃to760℃toprecipitateZr(CrFe)2.Athermoelectricpower(TEP)techniqueandtransmissionelectronmicroscopy(TEM)wereusedtomonitorthisprecipitationprocess.UsingtheJohnson-Mehl-Avramiequation,theTEPresultsandalineregressionmethod,theactivationenergyfordiffusionandthediffusioncoefficientofchromium(andFe)inα-Zrhavebeencalculatedover650℃~760℃.Thetemperaturedependenceofthediffusioncoefficient,DCr/α(cm2/s)isdescribedat650℃~760℃bytherelationshipformula.ThecoarseningoftheZr(CrFe)2particlesshowsat1/2dependenceofmeanparticlesizeonagingtime,t.Suchatimedependenceistypicalofcoarseningwhereatomtransferacrosstheinterfaceisrate-controlling.
简介:在自我组织的TiO2nanotubes(Pt-TiO2/Ti)上支持的铂nanoparticles用cathodic减小跟随的电气化学的阳极的氧化被准备。结构和Pt-TiO2/Tielectrocatalyst的化学自然被X光检查衍射(XRD)和扫描电子显微镜学(SEM)调查。XRD和SEM结果在nanotubularTiO2上显示铂的存在。磅存款的稳定性被周期的voltammetry也在0.5mol/LH2SO4答案调查。当退火了到锐钛矿时,Pt-TiO2/Ti催化剂的electrocatalytic活动在甲醇的电镀物品氧化期间展出改进效果。Pt-TiO2/Tielectrocatalyst上的甲醇氧化的连续周期的voltammograms看唯一的electrocatalytic特征是否与体积磅催化剂上的甲醇氧化相比。当一部electroactive电影的形成发生到工作催化剂表面上时,这因为由自我组织的TiO2nanotubes上的磅粒子的磅(111)方面的吸附的公司的进一步快的氧化。
简介:Byanoveltechnique-cathodicmicro-arcelectro-deposition(CMED),ZrO2coatingsweredepositedonanFeCrAlalloy.ExperimentalresultsshowthatthenecessaryconditionsforobtainingZrO2coatingsaretoapplyapulsepeakvoltageoveracriticalvalueandaddmoderateamountsofZrO2colloidalparticlesandZr(NO3)4intheequeoussolution.Theas-depositedcoatingsareporousbecausehydrogen,water,andothervaporsaregeneratedandreleasedfromthecoatingstothesolutionduringthesparkreaction.ThecoatingscontainmonoclinicandtetragonalcrystallineZrOwithcertaindegreeofamorphousstructure.TheprocessingparametersandmechanismofCMEDwerediscussed.
简介:Aseriesoftheelectrochemicalandlong-termcorrosiontestswascarriedoutina3.5wt%Na2SO4solutiononthermal-sprayedWC-17CoandWC-10Co-4Crcermetcoatingsinordertoexaminetheeffectofcompositionofbindermaterialsonthecorrosionbehavior.TheresultsrevealthattheoverallcorrosionresistanceoftheWC-17CocoatingisinferiortothatoftheWC–Co–CrcoatingsduetothecorrosionofbindermaterialswhichinduceWCparticlestofalloff.CoOandWO3oxidefilmsformonthesurfaceofWC-17CocoatinginNa2SO4solutionelectrochemicalcorrosionprocess,whichwillprotectthecoatingintheprocessofcorrosion.Cr2O3oxidefilmformedontheWC-10Co-4Crcoatingsurfacehasastronghinderedroletocorrosion.ThecorrosionmechanismofWC-17CocoatinginNa2SO4solutionisentirecorrosionofComatrix,whileitisfilm-holecorrosionmechanismforWC-10Co-4Crcoating.
简介:提出一种合成γ-LiAlO2的替代解决方案—改进燃烧法直接合成γ-LiAlO2,并将其用于相对简单的反应体系中,原料为非氧化性化合物如Al2O3和LiOH,燃料为尿素。采用1:1、1.5:1和2:1的非化学计量Li/Al摩尔比,在900和1000°C下反应5min,制备LiAlO2,并对其组织和结构进行表征。考察Li/Al摩尔比对材料形貌和高γ射线辐照下材料稳定性的影响。结果表明,所得粉体的晶体结构为?-LiAlO2和?-LiAlO2,其取决于Li/Al摩尔比。因此,用该方法可以成功合成微砖状、多面体状和层状?-LiAlO2,而无需任何后续处理。γ辐照结果表明,所得到的?-LiAlO2不分解,只形成少量的Li2CO3;由此可以确定,辐照会导致固结,不利于氚的有效提取;结果证明,用燃烧法生产高纯度?-LiAlO2不需要硝酸盐前驱体。
简介:ExtractingB2O3fromcalcinedboronmud(CBM)wasstudied.TheeffectoffactorssuchasreactiontemperatureandNaOH-to-CBMmassratioonB2O3extractionefficiencywasinvestigated.TheresultsshowthatincreasingreactiontemperatureandNaOH-to-CBMmassratioincreasesB2O3extractionefficiency.TherearetwostagesfortheB2O3extractingprocess:0–20ministhefirststage,whichisrapid;20–50ministhesecondstage,whichisslowerthanthefirststage.Theoverallextractingprocessfollowstheshrinkingcoremodel,andthefirstandsecondstagesaredeterminedtoobeythesurfacechemicalreactionmodelandthediffusionthroughtheproductslayermodel,respectively.Theactivationenergiesofthefirstandsecondstagesarecalculatedtobe41.74and15.43kJ·mol-1,respectively.TheB2O3extractingkineticsequationsofthefirstandsecondstagesarealsoobtained.
简介:钛氧化物涂层被微弧的氧化(毛)在Ti-2Al-2.5Zr合金底层上综合技术。涂层的表面特征被扫描电子显微镜学学习。当分泌物隧道尺寸随对待时间的增加清楚地增加时,Ti-2Al-2.5Zr合金的微弧的分泌物隧道减少。随涂层厚度的增加,多孔的层厚度显然增加。涂层的表面层的阶段作文被X光检查衍射和X光检查光电子光谱学评估。XRD和XPS分析的结果证明毛涂层主要由锐钛矿和金红石TiO2组成。