简介:Inthispaper,wehavedevelopedahighlyefficientmethodforthedirectpreparationofpropylenecarbonatefrompropyleneandcarbondioxide(CO2)usingquaternaryammoniumheteropolyphosphatotungstate–quaternaryammoniumhalidecatalyticsystemwithanhydroushydrogenperoxideasanoxidantthroughone-pottwo-stepprocess.Theeffectsoftheamountoftetrabutylammoniumbromide(TBAB),theconcentrationofhydrogenperoxideandotherreactionconditionswereinvestigated.Thecatalystsystemgaveanoptimumpropyleneoxideyield(91%)at75°Cinoxidationstepandthehighestpropylenecarbonateyield(99%)at140°Cand3.0MPaincycloadditionstep.Basedontheresults,areactionmechanismhasbeenproposed.
简介:Ithasbeenreportedthattheminimalspatiallyextendedphytoplankton-zooplanktonsystemexhibitsbothtemporalregular/chaoticbehaviour,andspatiotemporalchaosinapatchyenvironment.Asafurtherinvestigationbymeansofcomputersimulationsandtheoreticalanalysis,inthispaperweobservethatthespiralwavesmayexistandthespatiotemporalchaosemergewhentheparametersarewithinthemixedTuring-Hopfbifurcationregion,whicharisesfromthefar-fieldbreakupofthespiralwavesoveralargerangeofdiffusioncoefficientsofphytoplanktonandzooplankton.Moreover,thespatiotemporalchaosarisingfromthefar-fieldbreakupofspiralwavesdoesnotgraduallyinvadethewholespaceofthatregion.Ourresultsareconfirmedbynonlinearbifurcationofwavetrains.Wealsodiscussecologicalimplicationsofthesespatiallystructuredpatterns.
简介:Entangledphotonsarethefundamentalresourceinquantuminformationprocessing.Howtoproducethemefficientlyhasalwaysbeenamatterofconcern.HereweproposeanewwaytoproducecorrelatedphotonsefficientlyfrommonolayerWS2basedonboundstatesinthecontinuum(BICs).TheBICsofradiationmodesinthemonolayerWS2arerealizedbydesigningthephotoniccrystalslab-WS2-slabstructure.Thegenerationefficiencyofcorrelatedphotonpairsfromsuchastructurehasbeenstudiedbyusingarigorousquantummodelofspontaneousparametricdown-conversionwiththeplanewaveexpansionmethod.ItisfoundthatthegenerationefficiencyofcorrelatedphotonpairsisgreatlyimprovedifthesignalandidlerfieldsarelocatedattheBICsdeterminedbytheinversescatteringmatrixofthestructure.Thisisincontrasttotheparametricdown-conversionprocessfortheenhancedgenerationofnonlinearwavesifthepumpfieldislocatedattheBICsdeterminedbythescatteringmatrixofthestructure.Thegenerationrateofthecorrelatedphotonpairscanbeimprovedby7ordersofmagnitudeinsomedesignedstructures.Thegeneratedquantumsignalsaresensitivetothewavelengthandexhibitnarrowedrelativelinewidth,whichisverybeneficialforquantuminformationprocessing.
简介:怪物状态在1D数组被学习了,并且许多不同怪物状态用不同模型被发现了。研究最近被扩大了到2D数组,但是仅仅到他们的阶段模型。这里,我们把它递非局部的联合的影响上的神经原和焦点的2D数组的一个nonphase模型。用广泛的数字模拟,令人惊讶地,我们发现这个系统能显示出以前观察的怪物状态的大多数类型,与以前的模型相对照,在怪物状态的仅仅或一些类型能在每个模型被观察的地方。我们也发现这个模型能显示出象gridding那样的一些特殊像怪物的模式和multicolumn模式,它以前仅仅在阶段模型被观察。进一步,我们在场一条有效途径,即,移开联合的一些连接,产生异构的联合,它导致多样的像怪物的模式并且甚至从一个像怪物的模式导致转变到另外一个。
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简介:Thecreationandpropagationoflongitudinalacousticphonons(LAPs)inhighqualityhematitethinfilms(α-Fe2O3)epitaxiallygrownondifferentsubstrates(BaTiO3,SrTiO3,andLaAlO3)areinvestigatedusingthefemtosecondpump–probetechnique.Transientreflectionmeasurements(?R/R)indicatethephoto-excitedelectrondynamics,andtheinitialdecaylessthan1psandtheslowdecayof~500psareattributedtotheelectron-LOphononcouplingandelectron–holenonradiativerecombination,respectively.LAPsinα-Fe2O3filmcanbecreatedbyultrafastexcitationoftheligandfieldstate,suchastheligandfieldtransitionsunder800-nmexcitationaswellastheligandtometalcharge-transferwith400-nmexcitation.Thestrainmodulationsofthesoundvelocityandtheout-of-planeelasticpropertiesaredemonstratedinα-Fe2O3filmondifferentsubstrates.
简介:Themajorcausesofthesoundpressurelevel(SPL)variationduetothechangesoftheinclinedangleofacircularcylinderandtheaspectratio(ratioofdistancebetweenendplatestocylinderdiameter)wereinvestigated.Thevelocityfluctuationofthewakeandthesurfacepressurefluctuationofthecylinderweremeasuredinalownoisewindtunneltofindthecorrelationlength,coherentoutputpowerandStrouhalnumber.TheresultsshowthatthechangesofthesevaluesqualitativelycorrespondwiththechangeofSPL.Flowvisualizationtestsareperformedtoclarifythevariationofwakeinrelationwithinclinedangleandaspectratio.ItisfoundthatthespanwisestructureofKarman’svortexstreetisbrokendownbytheupwardflowsgeneratedaroundthebottomendplate,andthedegreeoftheinterferencebetweentheupwardflowandKarman’svortexstreetissmallerwhentheaspectratioislarger.
简介:Withthedevelopmentofultraintenseterawatt(TW)andpetawatt(PW)lasersystems,powerfulterahertz(THz)radiationfromlaser–plasmainteractionshasbeenreported.Plasma-basedTHzsystems,whichareusuallyoperatedatextremelylowrepetitionrates,callforsingle-shotdiagnostics.Inthispaper,variousstate-of-the-artsingle-shotdetectionmethodsareintroducedordesignedformeasurementsandapplicationsinvolvedinhigh-powerplasma-basedTHzsciences.
简介:Monolithicwhite-light-emittingdiodes(whiteLEDs)withoutphosphorsaredemonstratedusingInGaN/GaNmultiplequantumwells(MQWs)grownonGaNmicroringsformedbyselectiveareaepitaxyonSiO2maskpatterns.Themicroringstructureiscomposedof{1-101}semi-polarfacetsanda(0001)c-plane,attributedtofavorablesurfacepolarityandsurfaceenergy.ThewhitelightisrealizedbycombiningshortandlongwavelengthsofelectroluminescenceemissionsfromInGaN/GaNMQWsonthe{1-101}semi-polarfacetsandthe(0001)c-plane,respectively.ThechangeintheemissionwavelengthsfromeachmicrofacetisduetotheIncompositionvariationsoftheMQWs.Theseresultssuggestthatwhiteemissioncanpossiblybeobtainedwithoutusingphosphorsbycombiningemissionlightfrommicrostructures.
简介:Thetime-delaysignature(TDS)ofchaosoutputina1550nmvertical-cavitysurface-emittinglaser(VCSEL)subjecttofiberBragggrating(FBG)feedbackisinvestigatedexperimentally.Autocorrelationfunction(ACF)andmutualinformation(MI)areusedforquantitativelyidentifyingtheTDSofchaos.Forvariousbiascurrents,theTDSevolutionwiththefeedbackstrengthisdifferent,astheFBGprovideswavelength-selectivefeedback.Furthermore,basedontheTDSmapoftheFBGfeedbackVCSEL(FBGF-VCSEL)intheparameterspaceoffeedbackstrengthandbiascurrent,theoptimalTDSsuppressionregions,wherethedominantpolarizationmodeofFBGF-VCSELlocatesattheedgeofthemainlobeofFBGreflectionspectrum,havebeendetermined.Finally,forcomparativepurpose,theTDSofchaosinmirrorfeedbackVCSEL(MF-VCSEL)alsohasbeenpresented,andtheresultsshowthatanFBGF-VCSELpossessesbetterTDSsuppressionperformancethananMF-VCSEL.
简介:Adoptingthecharge-dependentArgonneV_(18)plusmicroscopicthree-bodyforces,theequationofstate(EOS)andsingleparticlepropertiesofsymmetricnuclearmatterhavebeeninvestigatedinBrueckner-Hartree-Fock(BHF)framework~[1].Themicroscopicthree-bodyforcemodel