学科分类
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51 个结果
  • 简介:不同尺寸的喷雾器被一个安德森空气刺绣花样收集观察黑碳(BC)的详细形态学与另外的伴随的喷雾器化学上被分开的喷雾器,用与一个精力DispersiveX光线分光计(SEM-EDX)装备的一台扫描电子显微镜。结果显示大多数BC喷雾器是在直径并且与同类的表面的大约50nm的球形的粒子。结果也证明这些粒子与另外的喷雾器或与自己一起聚集形成更大在测微计范围聚结。这些50-nmBC球形的粒子的形状被发现很类似于免除石油动力的车辆的内燃机的BCparticles的。这些球形的BCparticles被显示与发现帮助usingMatrix的激光解吸附作用/电离蒂米夫莱特·马斯·斯佩克特罗梅特里(MALDI-TOF-MS)的以前报导的fullerenes不同。

  • 标签: 大气粒子 纳米级颗粒 黑碳气溶胶 形态学 SEM-EDX
  • 简介:骨胶原纤维提供成为强壮的一个好例子微--或从nanoscaletropocollagen分子通过的mesoscale纤维一蹒跚并且以一种自底向上的方式的cross-linked组织。骨胶原纤维的建筑上的特征被显示出是一条有希望的途径开发高效的碳nanotube(CNT)纤维的Mimicking。在现在的工作,一个有弹性的模型被开发在bioinspiredCNT捆以内描述负担转移和失败繁殖,并且与象CNT方面比率和纵的差距那样的很多个几何、物理的参数建立捆的机械性质的关系,接口交叉结合密度,和在CNT的导致functionalization的降级,等等。与模型一起,沿着CNTCNT接口以及在每单个CNT的压力分布是捕获的井,和沿着CNT捆的机械性质上的接口和它的效果的失败繁殖被预言。工作可以在实践为新奇CNT纤维的设计提供有用指南。

  • 标签: 碳纳米管 弹性模型 仿生设计 纳米管束 胶原纤维 机械性能
  • 简介:Carbonnanotubemacro-filmsaretwo-dimensionalfilmswithmicrometerthicknessandcentimeterbycentimeterin-planedimension.Thesecarbonnanotubemacroscopicassemblieshaveattractedsignificantattentionfromthematerialandmechanicscommunitiesrecentlybecausetheycanbeeasilyhandledandtailoredtomeetspecificengineeringneeds.Thispaperreportstheexperimentalmethodsonthepreparationandcharacterizationofsingle-walledcarbonnanotubemacro-films,andastatisticalmechanicsmodelon...

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  • 简介:Nanofibrous碳的材料(NFC)作为有许多应用的材料的一个新班,能催化H2S的选择氧化到硫。在在H2S氧化的NFC结构和它的活动和选择之间的关联是坚定的。如果有更多的订的结构的NFC被综合,在碳的原来的催化剂的部分被增加在催化剂积累的碳减少,选择能被改进,这被表明。

  • 标签: 纳米结构 碳纳米纤维 碳纳米管 碳产率 氧化选择 硫化氢
  • 简介:Heattransportisakeyenergeticprocessinmaterialsanddevices.Thereducedsamplesize,lowdimensionoftheproblemandtherichspectrumofmaterialimperfectionsintroducefruitfulphenomenaatnanoscale.Inthisreview,wesummarizerecentprogressesintheunderstandingofheattransportprocessinlow-dimensionalmaterials,withfocusontherolesofdefects,disorder,interfaces,andthequantummechanicaleffect.Newphysicsuncoveredfromcomputationalsimulations,experimentalstudies,andpredictablemodelswillbereviewed,followedbyaperspectiveonopenchallenges.

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  • 简介:Thispapergivesanoverviewonnonlinearporousflowinlowpermeabilityporousmedia,revealsthemicroscopicmechanismsofflows,andclarifiespropertiesofporousflowfluids.Itshowsthat,deviatingfromDarcy’slinearlaw,theporousflowcharacteristicsobeyanonlinearlawinalow-permeabilityporousmedium,andtheviscosityoftheporousflowfluidandthepermeabilityvaluesofwaterandoilarenotconstants.Basedonthesecharacters,anewporousflowmodel,whichcanbetterdescribelowpermeabilityreservoir,isestablished.Thismodelcandescribevariouspatternsofporousflow,asDarcy’slinearlawdoes.Alltheparametersinvolvedinthemodel,havingdefinitephysicalmeanings,canbeobtaineddirectlyfromtheexperiments.

  • 标签: 低渗透多孔介质 非线性渗流 渗流模型 流体性质 低渗透油藏 微观机制
  • 简介:TheaerodynamicforcesandflowstructureofamodelinsectwingisstudiedbysolvingtheNavier-Stokesequationsnumerically.Afteraninitialstartfromrest,thewingismadetoexecuteanazimuthalrotation(sweeping)atalargeangleofattackandconstantangularvelocity.TheReynoldsnumber(Re)consideredinthepresentnoteis480(Reisbasedonthemeanchordlengthofthewingandthespeedat60%winglengthfromthewingroot).Duringtheconstant-speedsweepingmotion,thestallisabsentandlargeandapproximatelyconstantliftanddragcoefficientscanbemaintained.Themechanismfortheabsenceofthestallorthemaintenanceoflargeaerodynamicforcecoefficientsisasfollows.Soonaftertheinitialstart,avortexring,whichconsistsoftheleading-edgevortex(LEV),thestartingvortex,andthetwowing-tipvortices,isformedinthewakeofthewing.Duringthesubsequentmotionofthewing,abase-to-tipspanwiseflowconvertsthevorticityintheLEVtothewingtipandtheLEVkeepsanapproximatelyconstantstrength.ThispreventstheLEVfromshedding.Asaresult,thesizeofthevortexringincreasesapproximatelylinearlywithtime,resultinginanapproximatelyconstanttimerateofthefirstmomentofvorticity,orapproximatelyconstantliftanddragcoefficients.Thevariationoftherelativevelocityalongthewingspancausesapressuregradientalongthewingspan.Thebase-to-tipspanwiseflowismainlymaintainedbythepressure-gradientforce.

  • 标签: 空气动力学 NAVIER-STOKES方程 雷诺数 昆虫翅膀 边界涡流
  • 简介:Weconductedmeasurementsofblackcarbon(BC)aerosolinJiaxing,ChinaduringautumnfromSeptember26toNovember30,2013.WeinvestigatedtemporalanddiurnalvariationsofBC,anditscorrelationswithmeteorologicalparametersandothermajorpollutants.ResultsshowedthathourlymassconcentrationsofBCrangedfrom0.2to22.0μg/m3,withanaverageof5.1μg/m3.ThediurnaivariationofBCexhibitedabimodaldistribution,withpeaksat07:00and18:00.Themorningpeakwaslargerthantheeveningpeak.ThemasspercentagesofBCinPM2.5andPM10were7.1%and4.8%,respectively.TheabsorptioncoefficientofBCwascalculatedtobe44.4Mm-1,whichaccountedfor11.1%ofthetotalaerosolextinction.BCwasmainlyemittedfromlocalsourcesinsouthwesternJiaxingwhereBCconcentrationsweregenerallygreaterthan11μg/m3duringthemeasurementperiod.CorrelationanalysisindicatedthatthemainsourcesofBCweremotorvehicleexhaust,anddomesticandindustrialcombustion.

  • 标签: 黑碳气溶胶 嘉兴 秋季 中国 质量浓度 可吸入颗粒物
  • 简介:Thisworkfocusesonthestudyoftheeffectofhydrophobicityonthewaterflowincarbonnanotubes(CNTs)usingamoleculardynamics(MD)approachforawiderangeofpotentialapplicationssuchaswaterpurificationandhighefficiencyofnanofluidenergyabsorptionsystems(NEAS).ThehydrophobicitybetweenliquidwaterandsurfaceofCNTswascharacterizedbyinteraction-energy-coefficient(IEC)—aparameterdescribingtheenergyinteractionstrengthbetweenwatermoleculesandcarbonatoms.Itisshownthatthestaticcontactanglesbetweenwaterandcarbonsurfacedecreasefrom155°to44°whenthevaluesofIECincreasefrom0.042kJ/molto2.196kJ/mol.Inaddition,thepressuredropsinCNTbecameindependentofIECwhentheIECvaluewashigherthan1.192kJ/molforagivenflowrate.ItwasfoundthatthehydrophobicityofCNTsurfacehasasignificantimpactonthepressuredropofwaterflowintheCNTsandMDmethodprovidesaquantitativeevaluationoftheimpact.

  • 标签: Molecular dynamics Contact ANGLE Interaction-energy-coefficient Water
  • 简介:Holloworderedporouscarbonspheres(HOPCS)withahierarchicalstructurewerepreparedbytemplatingwithholloworderedmesoporoussilicaspheres(HOMSS).Scanningelectronmicroscopy(SEM)andtransmissionelectronmicroscopy(TEM)showedthatHOPCSexhibitedasphericalhollowmorphology.High-resolutionTEM,smallangleX-raydiffraction(SAXRD)andN2sorptionmeasurementsconfirmedthatHOPCSinverselyreplicatedtheunconnectedhexagonal-stackedporestructureofHOMSS,andpossessedorderedporosity.HOPCSexhibitedahigherstoragecapacityforLi+ionbattery(LIB)of527.6mAh/g,andgoodcyclingperformance.Alargecapacitylossduringthefirstdischarge-chargecyclewasfoundattributedtothehighcontentofmicropores.Thecyclingperformancewasderivedfromthehierarchicalstructure.

  • 标签: 高分辨透射电子显微镜 存储性能 中空 制备 碳球 多孔
  • 简介:高度强制的钴铁酸盐nanoparticles被他们的暂停的直接注射为加热为磁性的过高热综合并且学习进一个强壮的听觉频率的磁场的一个肿瘤和应用。物理(在液体和稳固的分散的动态磁性的磁滞现象和热产生),生物(在进老鼠肿瘤织物的治疗学的数量的粒子的毒性和穿入)象其它一样,粒子的性质被学习。一个模型被开发为Brownian和常规旋转与一篇报道在磁性的nanoclusters的暂停描述magnetodynamics,到提供观察现象的理解。开发的试验性、理论的技术为低频率的热产生为磁性的nanoparticles的可控制的合成形成了一个基础在医药并且另外的应用程序。

  • 标签: 钴元素 铁素体 磁悬浮液 动力磁现象
  • 简介:Coherentstructuresareessentialforthemomentumexchangeandturbulenceproductioninwall-boundedturbulentflows.Diversifiedcoherentstructureshavebeenobservedinturbulentboundarylayers,andhairpin-basedvorticesdominatemostoftherelevantliterature.However,thereisnoconsensusyetontheoriginandformingmechanismofhairpinvortices.Herein,fivecornerstonespertainingtotheframeworkofhairpin-basedcoherentstructuresarereviewed,andthreedifferenthairpingenerationmechanismsareclarified.Next,thetime-resolvedtomographicparticleimagevelocimetry(Tomo-PIV)isusedinanearlyturbulentboundarylayer(Reθ=420)toinvestigatetheoriginofhairpinvortices.Thetimelinesrevealatriangularbulgeinthelow-speedstreak(LSS),andtheinitialroll-upoccursattwosidesofit.Meanwhile,thematerialsurfacesmanifestasathree-dimensional(3D)wavestructureintheLSS,whichmaysupportthemodelofasoliton-likecoherentstructure(SCS).Subsequently,themethodofLagrangian-averagedvorticitydeviationisusedtodetectearlyvortices.Wefindthatthe3Dwavestructureisflankedbytwovortices,thusconfirmingtheroll-upoftimelinesanddemonstratingtheadvantageoftheLagrangiancriteriaincapturingstructuresincomplexflows.Theseresultssuggestthatvariouscoherentstructuresmayevolvefromthemetamorphosisof3Dwavestructuresandtheirlaterinteraction.Finally,thelimitationsoftraditionalexperimentalandpost-processingtoolsarediscussed.

  • 标签: COHERENT STRUCTURE HAIRPIN vortex SOLITON-LIKE COHERENT
  • 简介:Analumina-supportedcobaltaerogelcatalystpreparedfromasol-gelandasupercriticaldryingmethodwasusedinthecatalyticdecompositionofmethane.Thephysical-chemicalpropertiesofthecatalystwerecharacterizedanditsactivityformethanedecompositionwasinvestigated.Theeffectsofcalcinationandreactiontemperaturesontheactivityofthecatalystandthemorphologyofthecarbonnanotubesproducedwerediscussed.ACoAl2O4spinelstructureformedinthecalcinedcatalyst.Thequantityofthenanotubesproducedinthereactionincreaseswiththeamountofcobaltinthereducedcatalyst.Ahigherreactiontemperatureleadstoahigherreactionrate,thoughfasterdeactivationofthecatalystoccurswiththechange.Thecarbonnanotubesgrownonthecatalysthavesmoothwallsanduniformdiameterdistribution.

  • 标签: 碳纳米管 溶胶凝胶体 催化分解 钴催化剂 气凝胶
  • 简介:Thediscoveryofdrawablecarbonnanotubeforestsopenedupthepossibilityofconstructingawiderangeofpurecarbonnanotubemacrostructuresandsparkedinterestsindevelopingapplicationsfromthesestructures,especiallypurecarbonnanotubeyarns.Thisreviewexaminesthevariousfacetsofthedrawablecarbonnanotubeforests,synthesisanddrawability,andtheirresultingyarns,structure,production,propertiesandapplications.Thestructure,formationandpropertiesofcarbonnanotubeyarnsarecomparedwiththoseofconventionaltextileyarnsinordertoobtainabetterunderstandingofthescience,structuralmechanicsandprocessingtechnologyinvolvedincarbonnanotubeyarns.

  • 标签: 碳纳米管 结构力学 应用程序 森林 生产 性能
  • 简介:Thepolarlowandtropicalcyclonetypevorticesovertopographyareassumedtobetheaxisymmetricalandthermal-windbalancedsystems,whicharesolvedasaninitialvalueproblemofalinearizedvortexequationsetincylindricalcoordinates.Therolesofthesensibleandlatentheating,friction,andtopographyinthestructureandintensificationofthepolarlowandtropicalcyclonetypevorticesareanalyzed.Theradialvelocity,verticalvelocity,azimuthalvelocity,andtheunstablegrowthrateincludingthetopographyeffectsareobtained.Itisshownthattheinteractionbetweentheflowandthetopographyplaysasignificantroleinthestructureandintensificationofthepolarlowandtropicalcyclonesystem.Theanalysisofthetopographytermindicatesthat,intheup-slopesideofthemountain,theradialinflowandtheverticalascentforcedbythemountaincanintensifythepolarlowandtropicalcyclonetypevortexandincreasetheunstablegrowthrate.However,intheleesideofthemountain,theradialinflowandtheverticaldescentforcedbythemountaincanweakenthepolarlowandtropicalcyclonetypevortexanddecreasetheunstablegrowthrateofthepolarlowandtropicalcyclonesystem.Inaddition,theevolutionaryprocessandthespatialstructureofthepolarlowobservedovertheJapanSeaon19December2003areinvestigatedwiththeobservationaldatatoverifythistheoreticalresult.

  • 标签: 极地低压 热带气旋 地形影响 模型 平衡系统 增长速度
  • 简介:Spacecraftsciencemissionstoplanetsorasteroidshavehistoricallyvisitedonlyoneorseveralcelestialbodiespermission.Theresearchgoalofthispaperistocreateatrajectorydesignalgorithmthatgeneratestrajectoryallowingaspacecrafttovisitasignificantnumberofasteroidsduringasinglemission.Fortheproblemofglobaltrajectoryoptimization,evenwithrecentadvancesinlow-thrusttrajectoryoptimization,afullenumerationofthisproblemisnotpossible.Thisworkpresentsanalgorith...

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