简介:Inthispaper,theequilibriumsurfacetensionandthedynamicsurfacetensionofaqueousTritonX100solutionattemperature25℃weremeasuredbymeansofWilhelmyplatemethodandmaximalbubblepressuremethodrespectively.Thedeterminedcriticalmicellarconcentration(cmc)ofTritonX-100at25℃is2.2×10^-4mol/dm^3.TheadsorptionmechanicsofTritonX-100atair/solutionwasdetermined.Forthesubmicellarconcentrationsitisdiffusion-controlled.Thediffusioncoefficientwascalculatedfromtheexperimentaldataintherangeofshortlimit.Intherangeoflongtimeadsorption,thesubsurfaceconcentrationisfittedfromthemeasureddynamicsurfacetensions.
简介:ToovercomethedeficienciesoftheexistingVerhulstGM(1,1)model,basedontheexistinggreytheory,anon-equal-intervaldirectoptimumVerhulstGM(1,1)modelisbuiltwhichchoosesamodifiedn-thcomponentx(n)ofX(0)asthestartingconditionofthegreydifferentialmodel.Itoptimizesamodifiedβvalueandthebackgroundvalue,andtakestwotimesfittingoptimization.Thenewmodelextendsequalintervalstonon-equal-intervalsandissuitableforgeneraldatamodellingandestimatingparameters...