简介:Leadisoneofthepoisonoustraceelementforhumanbody.Itisimportanttofindawayformeasuringcontentoflead.Deterninationofleadbyelectrochemistryisoneofamethod[1].Inthispaper,leadisdeterminedbysingle-sweeppolarography.Theabsorptionbehaviorofmeso-tetra(4-sulfonylphenyl)porphyrin(H2TPPS4)complexwithleadionhasalsobeenstudied.InNa2B4O7-NaOHsolutionwithpH=l0.5,thereductionpeaksoftheligandareP1(Ep1=-0.38V),P2(Ep2=-1.04V),whichpotentialsareobtainedvs.S.C.E.Whenleadionhasbeenaddedintoabovesolution.ThepeakcurrentofP1andP2decrease,andanewreductionpeakP3(Ep3=-1.10V)appears.ItshowsthattheTPPS4-Pb(Ⅱ)complexforms,andthismethodcanbeappliedtostudythecomplex.
简介:Amethodforrapiddeterminationofsiliconcontentinricewasintroduced.Thereliabilityofthismethodwasverifiedbyusingarecombinantinbredline(RIL)populationofricecrossZhenshan97B/Milyang46.Twohundredandforty-nineRILsweretransplantedintworeplications.Simplecorrelationcoefficientsonthesiliconcontentinthehull,flagleafandsteminricebetweenduplicatesamplesof498ricematerialswere0.97954,0.97026and0.98848,respectively.Tenrepresentativesampleswereselectedformeasurementusingthehigh-temperaturealkalinefusionmethod.Simplecorrelationcoefficientbetweenthesiliconcontentsdeterminedbythehigh-temperaturealkalinefusionmethodandbythepresentmethodis0.9993.
简介:Thedeterminationofthesoundpowerofasourceissimpleinareverberationchamber,butusuallylowervalvesareobtainedatlowfrequenciesthanthefree-spacevalue.Itisshownthatthesoundpowerdeterminedinareverberationchamberdependsnotonlyonitsfree-spacepower,butalsoonthepositionsofthesourceandthereveiver,aswellasthewaythemeasurementsaremadeandaveraged.Exactandstatisticalformulasarederivedtoaccountforthesefactors.Theresultsexplainthediscrepancyandagreewellwithearlierexperiments.Basedonthetheory,parcticabletechniquesofsoundpowerdetermina-tionarepropesedandcorrectpowerformulaspresented.
简介:Thispaperfirstdevelopstheapproachestodeterminethegeopotentialofthelocalmeansealevel,andtheninvestigatestheoffsetofthe1985verticaldatumsurfacedefinedbythemeansealevelofYellowSeaattheDagangTideGaugeinQingdaocityusingthedevelopedapproachesandGPS/levelingdata.Itshowsthatthegeopotentialofthelocalmeansealevelatthetidegaugeisequalto62636853.5±0.2m2*s-2andthatthe1985verticaldatumsurfaceis24.6±5.4cmabovethegeoidrealizedbythegeopotentialW0=62636856.0±0.5m2*s-2.
简介:Fracturetoughnessisoneofthecrucialmechanicalpropertiesofbrittlematerialssuchasglassesandceramicswhichdemonstratecatastrophicfailuremodes.Conventionalstandardizedtestingmethodsadoptedforfracturetoughnessdeterminationrequirelargespecimenstosatisfytheplanestraincondition.Asforsmallspecimens,indentationisapopular,sometimesexclusivetestingmodetodeterminefracturetoughnessforitcanbeperformedonasmallflatareaofthespecimensurface.Thisreviewfocusesonthedevelopmentofindentationfracturetheoriesandtherepresentativetestingmethods.Crackingpatterndependentonindentergeometryandmaterialpropertyplaysanimportantroleinmodeling,andisthemainreasonforthediversityofindentationfracturetheoriesandtestingmethods.Alongwiththesimplicityofspecimenrequirementisthecomplexityofmodelingandanalysiswhichaccountsforthesemi-empiricalfeaturesofindentationfracturetests.Someunresolvedissuesshapingthegapbetweenindentationfracturetestsandstandardizationarealsodiscussed.更多还原
简介:Cashposition,heldbymutualfundwithpurposetosatisfyinvestors′redemption,willinevitablygeneratecertainamountofcost.Inthispaper,thetotalcostcausedbycashpositionisdividedintoopportunitycostandshortagecost,andamodelisconstructedtodescribetherelationshipbetweentotalcostandcashpositionalongwithinvestors′purchaseandredemption,fromwhichtheformulaofoptimalcashpositionisdeduced.Finally,theadjustmentofoptimalcashpositionindifferentmarketsituationsisdiscussed.
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简介:SmallX-rayScattering(SAXS)experimentusingSynchrotronRadiationasX-raysourcewasusedtodeterminetheaveragewallthicknessofmesoporoussilicaprepardbycondensationoftetraethylorthosilicate(TEOS)usingnon-ionicalkylpolyethyleneoxide(AEO9)surfactantastemplates.Theresultsagreedwiththatofhigh-resolutionTEM(HRTEM)measurement.
简介:TherewasasignificantcatalyticeffectoftraceGd(III)ionsontheoxidativereactionofpotassiumpersulfatewithSaffronTintheaceticacid–sodiumacetatebuffersolution.Thus,acatalytickineticfluorimetrymethodforthedeterminationoftraceGd(III)ionswasestablished.Thefactorssuchasacidity,concentrationofreagents,reactiontime,andtemperatureaswellasinfluenceofcoexistingionswerediscussed.Theoptimumreactionconditionswereestablished.Theapparentrateconstantandapparentactivationenergyofthereactionweredetermined.Thelinearrangeis0.02–0.10lgáml-1,andthedetectionlimitis7.27910-4lgáml-1.ThismethodwasusedforthedeterminationofgadoliniuminthesamplesoflanthanumacetatewithRSDof0.9%–3.1%.