简介：AnewtypeofcomplexsolidsuperacidcatalystWO3-ZrO2-SO42-withanacidstrengthH0≤-16.04waspreparedbykneadingZr（OH）4oramorphousZrO2withtungsticacid（H2WO4）（W/Zr=0.15）,followedbyexposingthiscomplexhydroxidesto0.5tool/LH2SO4,calcininginairat700～800℃for3h.ThiscatalystpossessesbothstrongBronstedacidityandstrongLewisacidityexperimentallyshowedbyIRobservationofpyridineabsorbedonit.XPSandAEStechniqueswereemployedtoexaminethevalencestatesoftungsten,zirconium,sulfurandtheirinteractions.Thestructureofsulfurspecieswasstudiedbyinfraredspectroscopyandastructuremodelofactivesitewasproposedupontheseresults.

简介：Rare-earthcompoundsolidsuperacidSO42-/TiO2/La3+wasprepared.Itscatalyticactivitywasexaminedunderdifferentsyntheticconditionsfortheesterificationofpropanoicacidandn-butylalcoholasprobingreaction.Theoptimumconditionswerealsofound,whichwerethepH=8,thedepositingtimewas24h,themassfractionofLa(NO3)3usedinsolidsuperacidwas5%,theconcentrationofH2SO4was1.25mol/L,thesoakingtimeinH2SO4was16handthecalciningtemperaturewas500°C.TheethyloleatewassynthesizedfromoleicacidandethanolinthepresenceofSO42-/TiO2/La3+.Theoptimumreactionconditionswereobtainedwhichwerethereactiontimewas6h,molarratioofoleicacidtoethanolwas1:4andthemassfractionofcatalystwas4%.

简介：固体太酸那么<潜水艇class=“a-plus-plus”>42/ZrO2-SiO2被剧降受精方法，和它的催化活动准备与p-nitrobenzoic酸和甲醇的酯化作用被测试。最佳条件也被发现，也就是说，在硅石和氧化锆之间的臼齿的比率是10:1，锻烧温度是550猠湩整楲杮愠摤瑩癩獥愠敲愠潤瑰摥?桴?琠?瀠慨敳琠慲獮瑩潩?景匠???汣獡?愢瀭畬?汰獵??猯'T举猼扵挠慬獳∽?汰獵瀭畬?????愠摮琠敨洠'炭鷳T?牰灯牥楴獥漠?桴?潣灭獯瑩獥愠?潢桴爠潯?整灭牥瑡牵?湡?楨桧琠浥数慲畴敲愠敲愠汬椠据敲獡摥眠瑩?浳污?硥整瑮