简介:本文采用高温团相反应合成TCaTiO3∶Pr3+红色发光材料、报道了Pr3+激活的CaTiO3的光谱特征及长余辉特性,并与CaS∶Eu的光谱特性及长余辉进行了比较。CaTiO3∶Pr3+将是一种具有广泛用途的新材料
简介:以苯甲酸、邻苯二甲酸、间苯二甲酸、水杨酸、丙烯酸、甲基丙烯酸、α-噻吩基三氟甲酰丙酮为第一配体,二安替比林甲烷,三正辛基氧化膦、2,2'-联吡啶、邻菲咯啉及邻菲咯啉N-氧化物为第二配体,合成了系列铕三元配合物.经元素分析确定了它们的组成;研究了它们的紫外吸收光谱、红外吸收光谱及荧光光谱.紫外光谱的研究表明,配合物的紫外吸收主要表现为配体的吸收,但是吸收峰的位置发生了移动;红外光谱的研究表明,配合物的红外光谱不同于自由配体的红外光谱,在400~500cm-1出现了吸收峰,这是Eu-O的伸缩振动峰;荧光光谱的研究表明,第二配体的加入可以显著提高配合物的荧光性能.
简介:(Y,Gd)BxV1-xO4-x:Eu3+phosphorswerepreparedbysolidstatereaction.Theredemissioncolorpurityof(Y,Gd)BxV1-xO4-x:Eu3+phosphorismuchbetterthanthatoftherecentwidely-usedcommercialredemittingphosphor(Y,Gd)BO3:Eu3+anditsrelativeemissionintensityis84%ofthecommercialphosphor(Y,Gd)BO3:Eu3+.Itisexpectedthat(Y,Gd)BxV1-xO4:Eu3+phosphorwillbeapromisingcandidateforPDP(plasmadisplaypanels)application.
简介:CeO2andCuOx-CeO2supportedpotassiumcatalystsweresynthesizedbywetnessimpregnationmethod.ThecatalystswerecharacterizedbyBET,NO-TPO,NOx-TPDandsoot-TPOmeasurements.Bythedecorationofpotassiumandcopper,themaximumsootcombustiontemperatureoftheceria-basedcatalystdecreasedto338and379°CinthepresenceandabsenceofNOunderaloosecontactmode,re-spectively.ThepronouncedlyenhancedNOoxidationabilitybycopperintroductionandNOxstoragecapacitybypotassiummodif...
简介:BasedonAPISTD1104-2005andCSAZ662-2007,fieldgirthweldingtestsandgirthweldabilityevaluationswereexecutedforthreetypesofwallthicknessX70UOEpipeline,inwhichthemostpopularmainlinegirthweldingmethod,single-wireautomaticgasmetalarcwelding(GMAW),wasused.Theweldingprocedurespecificationwasoptimizedtoachieveagoodqualityandcold-crack-freegirthweldjointwithoutpreheatingorpost-weldheattreatment.Inaddition,porosities,inclusions,andincompletefusiondefectswereavoided.Thetensilestrength,bending,Vickershardness,CharpyV-notchimpacttoughness,andcracktipopeningdisplacementfracturetoughnessofthegirthweldjointwereevaluated,andthejointexhibitedgoodmechanicalperformance.Thus,thefieldgirthweldabilityofBaosteel’sX70UOEpipelineisexcellentforautomaticGMAW.