学科分类
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420 个结果
  • 简介:Pr2Fe14B-La2Fe14B系统被衍射(XRD),微分扫描热量测定(DSC)和扫描电子显微镜学(SEM)与精力装备了的X光检查粉末调查散X光检查光谱学(版本)。水晶结构参数被完整侧面的Rietveld精炼决定。结果揭示了那所有合金(Pr1-xLax)2Fe14B使Nd2Fe14有空格组P42/mnm的B类型结构并且形成了连续固体在x=0.0之间的解决方案并且1.0。格子参数一,c,单位房间体积V和c/a比率与La集中线性地增加了。由thermogravimetry分析决定了,居里温度(TC),阶段转变温度和融化的温度(Pr1-xLax)2Fe14B在La内容之上线性地减少了。基于DSC大小和X光检查粉末衍射考试的结果,Pr2Fe14B-La2Fe14B系统被建立。

  • 标签: 水晶结构 格子参数 居里温度 热分析 稀土元素
  • 简介:Theeffectsofthefinalelectromagneticstirring(EMS)onthesolidificationstructureof60Si2CrVAThighstrengthspring(HSS)steelofcontinuouscasting(CC)billetshasbeenstudied.Theanalysisofthesolidificationstructureisbasedonthecomparisonbetweenthemacrostructure,microstructure,carbonsegregationanddefectsofthe60Si2CrVATbilletwithmold-electromagneticstirring(M-EMS)andthosewiththeM+finalsolidificationzoneelectromagneticstirring(F-EMS).ItisfoundthatthesolidificationstructureofthebilletwiththeF-EMSisimprovedwiththetightnessofthebilletandtheincreaseintheratiooftheequiaxedstructure,theinnerporosityandtheshrinkageareremarkablyreduced,andthattheratioofcentralcarbonsegregationsharplydecreases.Meanwhile,thesecondarydendritearmspacing(SDAS)isimproved,andtheratioofcentralequiaxedgrainconsiderablyincreases,whichresultsinfinergrains.Therefore,thequalityofthebilletisenhancedwiththeF-EMS.

  • 标签: 环境管理体系 凝固组织 钢坯质量 弹簧钢 电磁搅拌 凝固结构
  • 简介:对304不锈钢2B板表面边鳞缺陷进行扫描电镜和能谱分析,并结合其整个生产工艺参数分析,得出铁素体当量高是导致边鳞缺陷发生的主要原因。根据上述原因提出了相应的改进建议。

  • 标签: 304不锈钢 2B板 边鳞
  • 简介:Theaimofthisresearchistopulseco-depositnano-CeO2particlesintoNi-W-Balloycoatingsinordertoimprovethesurfaceproperties.Theinfluenceofpulsefrequencyanddutycircleondepositionrate,microhardnessandmicrostructures,andtheinfluenceofheattreatmenttemperatureonphasestructures,microhardnessandabrasivityofNi-W-B-CeO2compositecoatingswereinvestigated.Theresultsindicatedthatthepulseco-depositionofnickel,tungsten,boronandnano-CeO2particlefromthebathwhichnano-CeO2particlewassuspendedbyhighspeedmechanicalstirringledtotheNi-W-B-CeO2compositecoatings,possessingbettermicrohardnessandabrasionresistancewhenheat-treatedat400℃for1h.Themicrohardnessas-depositedwith636Hzandthedepositionratewith0.0281mm·h-1wasthehighestatpulsefrequencywith1000Hzandpulsedutycirclewith10%.Microstructuresanalysisdisplaysthatdecreasingpulsedutycycleleadstorefinementingrainstructuresandtheimprovementofmicrostructures.X-raydiffractionshowsthatthecompositecoatingas-depositedwasmainlyintheamorphousstateandpartiallycrystallized,butwhenheattreatedat400℃,thecrystallizationtrendwasstrengthenedfurther.

  • 标签: pulse ELECTRODEPOSITION composite coatings deposition rate
  • 简介:就10/0.4kV变电所低压侧中性点的接地形式、PE线在配电箱的接法、打人工接地极的必要性等问题进行了阐述,以便在日后设计、施工时避免不必要的返工,造成人力物力的浪费。

  • 标签: 变电所接地 人工接地极 剩余电流监测 TN-C-S PE线
  • 简介:有一致形态学的新奇红射出的K2(Ge,Si)F6:Mn4+黄磷被一起沉淀方法综合。纯K2有P636阶段>除P3m1空间组以外的mc空间组就被Si的加入在K2在房间温度的GeF6根据XRD描述。薄片状的显示出的SEM图象和为K2GeF6:Mn4+和K2(Ge,Si)F6:Mn4+黄磷分别地。光致发光刺激(PLE)和光致发光(PL)在K2GeF6:Mn4+和K2(Ge,Si)F6:Mn4+系统。并且K2有Si的GeF6:Mn4+显示出一座强壮的山峰。同时水晶的地包围Mn4+变化能在这个氟化物系统影响腐烂时间。带的设备的颜色范围基于K2(Ge,Si)F6:Mn4+和K2分别地,GeF6:Mn4+到达了多达94.58%NTSC(国家电视标准委员会)和94.386%NTSC那基于氮化物红黄磷比那高得多。在K2(Ge,Si)F6:Mn4+黄磷的所有这些原来的特征作为为改善灯光和常规白LEDs的显示质量的红黄磷为潜在的应用是合乎需要的。

  • 标签: 红色荧光粉 白光LED SI Ge 发光性能 合成
  • 简介:TheNd60Fe20Al8Co10B2alloywaspreparedbysuctioncastingofthemoltenalloyintoacoppermoldunderargonatmosphere.Themicro-structuralandmagneticpropertychangesintheNd60Fe20Al8Co10B2alloyduringcrystallizationwereinvestigatedbyX-raydiffraction(XRD),differentialscanningcalorimetry(DSC),scanningelectronmicroscope(SEM)andthevibratingsamplemagnetometer(VSM).TheprecipitationandNd-richandFe-richphaseshavenosignificanteffectontheintrinsiccoercitityforNd60Fe20Al8Co10B2alloyannealedbelow723K.However,thegrowthofFe-richphasedecreasesthesaturatemagnetizationandremanenceofthealloy.Thehardmagneticbehaviorisdisappearedwhenthealloyisfullycrystallized.

  • 标签: Nd60Fe20Al8Co10B2 铸造合金 结构 磁性能 XRD DSC
  • 简介:Withpricesformetalresourcessuchasnickelandmolybdenumsoaring,thereisaheightenedsenseofcrisisconcerningresourcescarcity.WhileType304,themostcommonstainlesssteel,offersexcellentcorrosionresistance,itspriceisaffectedsignificantlybythecostofnickelbecauseofits8%nickelcontent.ThestainlesssteelthathasthesamecorrosionresistanceasthatofType304anddoesnotcontainnickelandmolybdenumhasbeenrequired.JFESteelCorporationhasdevelopedanew21%Cr-0.4%Custainlesssteel,theworld’sfirstferriticstainlesssteel,whichoffersequivalentcorrosionresistancetoType304whilecontainingabsolutelynonickelormolybdenum,tworaremetals.Thenewlydevelopedsteelcontains21%chromiumwiththeadditionof0.4%copper.Thedevelopmentofthesteelisbasedonanewdiscoverythatthepassivefilmsofstainlesssteelscouldbestrengthenedbythesynergyeffectofhighchromiumcontentandcopperaddition.Copperadditionenrichesthechromiumcontentinpassivefilmsafterfieldexposure.Newlydeveloped21%Cr-0.4%CustainlesssteelisadoptedformanyapplicationsasasubstitutionforType304,includingcommercialkitchenware,buildingmaterialsandindustrialmachinery.ThesteelisexpectedtobeanewstandardofaferriticstainlesssteelasasubstitutionforType304.

  • 标签:
  • 简介:EffectsofNbandZrsubstitutionsonthecrystal]izationbehaviorsandmagneticpropertiesofmelt-spun(Nd,Pr)2Fe14B/α-Fealloyswerestudied.Theresultsshowthatfor(Nd0.4Pr0.6)8.5Fe85.5B6ribbons,themetastable(Nd,Pr)3Fe62B14precipitatesaftertheinitialcrystallizationofα-Feanddecomposesintothefinalmixtureof(Nd,Pr)2Fe14Bandα-Fe.For(Nd0.4Pr0.6)8.5Fe84.5Zr0.5Nb0.5B6ribbons,however,(Nd,Pr)2Fe14Bandα-Fephasesprecipitatesimultaneously.ThisindicatesthatbothNbandZrdopingcanavoidtheformationofmetastablephaseand!

  • 标签: 稀土 磁性材料 磁力结构
  • 简介:有TbCu7结构的SmCo6.6Nb0.4nanoflakes被帮助表面活化剂的高精力球milling(SA-HEBM)成功地作为milling媒介与heptane和油的酸准备。微观结构,水晶结构和磁性被分别地扫描电子显微镜学,X光检查衍射,和颤动的样品磁强计学习。nanoflakes的结晶的排列和coercivity系统地被调查的c轴上的球milling时间的效果。研究证明nanoflakes有100nm的平均厚度,1m的一条平均直径,与象100一样高的方面比率。作为时间从2~8h增加了的球milling,思考达到顶点紧张比率我(002)/I(101)显示了SmCo6.6Nb0.4阶段的c轴水晶质地的度,增加了第一,在4h到达了一座山峰,然后减少。同时,nanoflakes的coercivity也增加了第一,为4h在13.86kOe到达了一座山峰,然后减少。

  • 标签: 表面活性剂 晶体结构 高能球磨 磁学性质 纳米 制备
  • 简介:通过电化学分析与测试,研究B4C体积分数分别为20%、30%、40%的B4C/Al基复合材料及其基体合金(6061铝合金)在不同浓度及不同温度的硫酸溶液中的腐蚀行为。由动态极化曲线和阻抗谱得到相应的电化学参数,并利用阻抗分析软件对该复合材料和基体合金腐蚀过程的等效电路进行模拟,分析腐蚀机理,通过Arrhenius方程计算腐蚀过程中B4C/Al基复合材料与6061铝合金的反应活化能,并分析两者的焓变与熵变,对腐蚀前后2种材料界面的微观结构进行观察。结果表明:B4C/Al基复合材料在硫酸溶液中的腐蚀速率随B4C颗粒含量增加而增大,基体铝合金在硫酸中的耐腐蚀性能高于B4C/Al基复合材料。B4C/Al基复合材料和基体铝合金在硫酸中的腐蚀速率都随硫酸溶液浓度增加而增大;当溶液温度升高时,二者的腐蚀速率都快速增加。B4C/Al基复合材料和Al基体合金在硫酸溶液中的腐蚀都表现为明显的点蚀。铝基体材料在硫酸溶液中的反应活化能大于B4C/Al基复合材料,计算所得活化焓与活化熵的值均表明复合材料的腐蚀反应比基体合金更容易进行,因而遭受腐蚀更严重。

  • 标签: B4C/Al复合材料 H2SO4溶液 电化学方法 显微组织
  • 简介:采用金相显微镜、扫描电子显微镜对82B盘条钢拉拔断裂试样进行了分析。结果表明,钢中较多的非金属夹杂物影响材料连续性,是盘条在拉拔过程中出现断裂的主要原因。

  • 标签: 夹杂物 断裂 82B
  • 简介:ThestructureandhydridingperformanceofLa0.6Nd0.4Ni4.8Mn0.2Cux(x=0~0.4)alloyswereinvestigatedinordertodevelopsuitablematerialsformetalhydrideairconditioner.TheeffectofCuadditiononthecrystalstructure,equilibriumpressure,hydrogencapacityandhysteresisaswellashydrogenabsorption/desorptionkineticsweresystematicallystudiedbyusingthemeasurementofP-Cisotherms,X-raydiffractionandscanningelectronmicroscopy.AstheamountofCuincreases,theplateaupressureincreasesandhydrogenabsorption/desorptionkineticsisimproved,buttheeffectivehydrogenstoragecapacitydecreases.Itisshownthatvariationsinthebasalplaneparameteracanbeusedasanindicationfortheplateaupressurechanges.Withtheincreaseofparametera,theplateaupressuredecreases.ForLa0.6Nd0.4Ni4.8Mn0.2Cux(x=0~0.4)alloysthereisarelationshipbetweentheeffectivehydrogenstoragecapacitiesandtheratiosoftheirunitcellparameterscanda.Theeffectivehydrogenstoragecapacitydecreaseswithincreaseofa/c.

  • 标签: metal HYDRIDE crystal structure HYSTERESIS KINETICS
  • 简介:以往地质资料对金川矿区2^#矿体F17以东41—50行1050m水平以下的研究程度较低,依托1050m水平开拓工程所提供的便利条件,在1050m水平平面开拓工程的上盘沿脉道,采用坑探与钻探相结合方式开展地质找矿。本次找矿项目在F17以东41-50行1050—850m和40—41^+25行1100—1050m勘探区段范围内新增资源储量378.82万吨。新增特富矿46.54万吨。

  • 标签: 地质找矿 F17以东 1050m以下 金川矿区
  • 简介:本文通过对三矿区F17以西扩能改造后,产能提高了2倍多,但其通风系统沿用了金川矿区一期工程的可用部分。产能的提高对原有通风系统带来的挑战,构建新的通风系统进行了阐述。提出了在保持F17以东、F17以西并联通风系统的前提下,构建新的F17以西通风系统,形成多中段风井回风接力的概念,通过新旧通风系统比较,阐明了新的多中段风井回风接力系统在生产中的优越性。建议具备类似条件时在生产中加以推广应用,对提高劳动生产率,减少系统新建费用,降低生产成本起到良好的作用。

  • 标签: 通风系统 构建 回风接力
  • 简介:Thesimplemodelfor4f-5dtransitionsoflanthanideionsincrystalswasextendedtodealwiththecaseoftheoctahedralcrystalfield,whereforthet2componentof5dorbitalsthespin-orbitinteractioncouldnotbeneglectedduetoincompletequenchingofthe5dorbitalangularmomentum.Theenergylevelsforthe4fN-15dconfigurationandtherelativelinestrengthsforthe4fN4fN-15dtransitionwerecalculatedindetail.Theresultwasappliedtotheinterpretationofthelow-temperature4f-5dexcitationspectrumofCs2NaYCl6∶Tb3+.

  • 标签: SIMPLE model f-d TRANSITION 5d SPIN-ORBIT
  • 简介:分析证明了温度和时间对SWRH77B盘条性能的影响。选择一组人工时效的试验条件,进行人工与自然时效方法的对比试验,通过试验验证了可以通过选定条件下的人工时效试验来代替自然时效试验。

  • 标签: SWRH77B盘条 自然时效 人工时效
  • 简介:Magnetizationanddemagnetizationcurvesandhysteresisloopsapplieddifferentmagnetizing.fieldsinsinteredNd-Fe-BandNd-Dy-Fe-Bmagnetsfromthermallydemagnetizedanddcfield-demagnetizedstateswereinvestigatedattemperaturesofupto150℃.Thefirst-quadrantremagnetizationcurvesandthecurvesofcoerciveforces_MH_CversusrernagnetizingfietdsH_mfromdcfield-demagnetizedstateatroomtemperatureshowasteparoundmagnetizingfieldasabsolutevalueofthemaximumintrinsiccoercivity.Thestepsof_MH_C-H_mcurvesshiftedtolowerremagnetizingfieldsandtheshapesofmagnetizationcurveschangedfromsteptypetoprecipitoustypewhentemperaturewentupto100~150℃orafterthespecimenwasthermallydemagnetizedatatemperaturehigherthantheCurietemperature.Thesteepriseofkneecoereivitywithincreasingmagnetizingfieldisbehindthatof_MH_C.NotethatthemagnetichardeninginsinteredNd-Fe-Bmagnetsiscontrolledbypinningofdomainwalls.

  • 标签: MAGNETIZATION COERCIVITY thermally HYSTERESIS ABSOLUTE walls