简介:采用喷雾干燥-氢气还原法制备出W-20wt%Cu超细复合粉末,并对由该复合粉末所制得的压坯进行了高温烧结,利用SEM、XRD等分析手段对复合粉末的特性和烧结体的组织进行了表征和观察。实验结果表明,由该方法制备的W-20wt%Cu超细复合粉末颗粒细小,平均粒径在200nm左右;喷雾干燥后的氧化物复合粉末在还原后产生了新的合金相(Cu0.4W0.6),还原后的复合粉末由Cu0.4W0.6相和Cu相组成,而且两相的晶粒度达到纳米级,其中Cu0.4W0.6相的晶粒约为33nm,Cu相的晶粒约为63nm;复合粉末具有很高的烧结特性,经高温烧结后合金致密度达到98%以上,而且金相组织分布均匀。
简介:AnumericalmodelAlloy/MhasbeenappliedtoinvestigatethemicrosegregationinAl-4.45wtpctCualloy.Thecalculateddatawerecomparedwiththeexperimentalmeasurementsforsamplessolidifiedatdifferentcoolingrates.Discrepanciesinsoluteconcentrationoccurbetweentheexperimentalobservationsandcalculatedresults.Reasonsforthediscrepancieswerediscussed,andtheeffectofdendritejoiningatalaterstageofsolidificationonthemicrosegregationwasinvestigated.Calculationsthathaveincludedthiseffectshowedabetterfitwithexperimentalresults.
简介:在团结微观结构的谷物结构和precipitates极端纯有不同Ti或Nbmicro-alloying的17wt%Cr以铁酸盐为主要成的不锈钢试验性地并且理论上被调查。到钢的Ti或Nb的增加减少了谷物尺寸(D)和延伸因素(E),这被谷物结构观察发现,并且改进了equiaxed谷物比例(P)和球状因素()。在学习的四钢之中,最小的谷物尺寸和最大的equiaxed谷物比例被联合把Ti和Nb加到钢获得。SEM观察显示了那几种猛冲例如锡,MC(在Nb的富人),等等,洗阶段(Fe2Nb)在相应的钢形成了。另外,用Thermo计算软件计算的结果说明了那听在合适的Ti和N内容在液体猛抛。同时,团结间隔(T)被Ti或Nb的增加扩大,并且Nb的有效性比Ti强壮。基于试验性并且计算结果,在equiaxed谷物比例的谷物精炼和增长的机制被讨论。
简介:TheW-Cucompositesarewidelyusedasweld-ingelectrodes,electronicpackagingmaterials,electricdischargematerialsandheatsinksbecauseoftheexcellentproperties.Inthisresearch,theW-40wt.%Cucompositeswerepreparedthroughthevacuumhot-presssinteringmethod,andtheeffectofsinteringtemperatureonthemicrostructureand
简介:Inpursuingexcellentsupercapacitorelectrodes,wedesignedaseriesofM0S2/C0S2compositesconsistingofflower-likedMoS2andoctahedron-shapedCoS2throughafacileone-stephydrothermalmethodandinvestigatedtheelectrochemicalperformanceofthesampleswithvarioushydrothermaltime.Duetothecouplingoftwometalspeciesandabigamountofwell-developedCoS2andMoS2,theresultsindicatedthattheMoS2/CoS2compositeselectrodesexhibitedthebestelectrochemicalperfor-mancewithalargespecificcapacitanceof490F/gat2mV/sor400F/gat10A/gamongallsamplesasthehydrothermaltimereached48h(MCS48).Furthermore,theretentionofMCS48is93.1%after10000cyclesat10A/g,whichmanifeststheexcellentcyclingstability.TheoutstandingelectrochemicalperformanceofMCS48indicatesthatitcouldbeaverypromisingandnovelenergystoragematerialforsupercapacitorsinthefuture.
简介:Inthepaper,theauthorsanalysetherela-tionshipbetweentheelectricalconductivityσofZrO2andthecontentofdopedstabilizingagentbythePositronAnnihilationTechnique,andexplainthechangetendencyofσwiththecontentofstabilizingagent.Theresearchshowsthat"numberofeffectivevacancy"inmaterialisadecisivefactorcausingchangeofσ.
简介:TheeffectoftitaniumadditiononthemicrostructureandmechanicalpropertiesofbrassCu40Znhasbeenstudiedviathepowdermetallurgy(P/M)route.Thewater-atomizedCu40Zn—1.0wt%Tialloypowderwasconsolidatedatdifferenttemperaturesintherangeof400—600℃usingsparkplasmasintering(SPS)andhotextrusionsubsequently.Resultsshowthatthesuper-saturatedsolidsolutiontitaniumelementinrapidlycooledbrassCu40Znpowdercreatedhighchemicalpotentialforaprecipitatereaction,showingsignificantgrainrefinementeffectsontheconsolidatedCu40Znmatrix.Consequently,excellentmechanicalpropertieswereobtainedbyprecipitationhardeningandworkhardeningaftersinteringandextrusion,withyieldstrengthof390MPa,ultimatetensilestrengthof617MPa,andVickersmicro-hardnessof192HV,whichare28.7%,23.4%,and23.9%highervaluesthanthoseofextrudedCu40Znbrass,respectively.
简介:(Ni0.81Fe0.19)0.66Cr0.34hasahighresistivityandacrystalstructureclosetothatofNi0.81Fe0.19.TheelectricalandX-raydiffractionmeasurementsprovethatathinNiFeCrseedlayerinducesawell(111)-orientedNi0.81Fe0.19film.Post-annealingtreatmentimprovesthemagneticpropertiesof(Ni0.81Fe0.19)0.66Cr0.34(45A)/Ni0.81Fe0.19(150A)/Ta(55A)thinfilmpreparedunderadepositionfield,whereastheinter-diffu-sionofNiFe/Tadeterioratesthemagnetoresistancepropertiesofthefilm.
简介:ThehomogeneousplasticflowoffullyamorphousandpartiallycrystallizedZr41.2Ti13.8Cu12.5Ni10Be22.5bulkmetallicglass(Vitl)hasbeeninvestigatedbycompressiontestsathightemperaturesinsupercooledliquidregion.Experimentalresultsshowthatatsufficientlylowstrainrates,thesupercooledliquidofthefullyamorphousalloyrevealsNewtonianflowwithalinearrelationshipbetweentheflowstressandstrainrate.Asthestrainrateisincreased,atransitionfromlinearNewtoniantononlinearflowisdetected,whichcanbeexplainedbythetransitionstatetheory.Overtheentirestrainrateintervalinvestigated,however,onlynonlinearflowispresentinthepartiallycrystallizedalloy,andtheflowstressforeachstrainrateismuchhigher.Itisfoundthatthestrainrate-stressrelationshipforthepartiallycrystallizedalloyatthegiventemperatureof646Kalsoobeysthesinhlawderivedfromthetransitionstatetheory,similartothatoftheinitialhomogeneousamorphousalloy.Thus,itisproposedthattheflowbehaviorofthenanocrystalline/amorphouscompositeat646Kismainlycontrolledbytheviscousflowoftheremainingsupercooledliquid.
简介:Nd_2Zr_2O_7isbeingexploredasanalternatethermalbarriercoating(TBC)materialforoperatingabove1300°C,andgreatefforthasbeenmadetoenlargeitsthermalexpansioncoefficient(TEC)andimproveitstoughness.Inthisstudy,Sc_2O_3wasdopedtoNd_2Zr_2O_7.Thephasestructure,TECsandtoughnessof((Nd_(1-x)Scx))_2Zr_2_O7(x=0,0.025,0.05,0.075,0.1)compoundswereinvestigated.((Nd_(1-x)Scx))_2Zr_2_O7(x=0,0.025,0.05,0.075)exhibitedpyrochlorestructure,while((Nd_(0.9)Sc_(0.1)))_2Zr_2O_7consistedofpyrochloreandfluoritephases.WiththeincreaseoftheSc_2O_3content,theorderingdegreeofthepyrochloreinthecompoundsdecreased.In((Nd_(1-x)Scx))_2Zr_2O_7series,((Nd_(0.925)Sc_(0.075)))_2Zr_2O_7exhibitedthelargestTEC,whilethetoughnessofthecompoundsincreasedwithincreasingtheSc_2O_3content.Therelatedmechanismswerediscussedbasedonthecrystalstructureanalysis.ConsideringtheTECandtoughness,10mol%Sc_2O_3wassuggestedastheoptimaldopingcontentforNd_2Zr_2O_7ceramic.