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简介：AdditionofAl-5Ti-1Balloytomoltenaluminumalloyscanrefineα-Algrainseffectivelyandtherebyimprovetheirstrengthandtoughness.TiAl3andTiB2inAl-5Ti-1Balloyarethemainsecondary-phaseparticlesforrefinement,whiletheunderstandingontheeffectoftheirsizesonα-Algrainrefinementcontinuestobefragmented.Therefore,Al-5Ti-1Balloyswithvarioussizesandmorphologiesofthesecondary-phaseparticleswerepreparedbyequalchannelangularpressing(ECAP).Evolutionofthesecondary-phaseparticlesduringECAPprocessandtheirimpactonα-AlgrainrefinementwerestudiedbyX-raydiffractionandscanningelectronmicroscope(SEM).ResultsshowthatduringtheECAPprocess,micro-cracksfirstlyappearedinsideTiAl3particlesandthengraduallyexpanded,whichresultedincontinuousrefinementofTiAl3particles.Inaddition,micro-distributionuniformityofTiB2particleswasimprovedduetotheimpingementofTiAl3particlestoTiB2clustersduringdeformation.ExcessivelylargesizesofTiAl3particleswouldreducethenumberofeffectiveheterogeneousnucleusandthusresultedinpoorgrainrefinementeffectiveness.Moreover,excessivelysmallTiAl3particleswouldreduceinhibitoryfactorsforgraingrowthQandweakengrainrefinementeffectiveness.Therefore,anoptimalsizerangeof18-22μmforTiAl3particleswassuggested.

简介：Nd_2Zr_2O_7isbeingexploredasanalternatethermalbarriercoating(TBC)materialforoperatingabove1300°C,andgreatefforthasbeenmadetoenlargeitsthermalexpansioncoefficient(TEC)andimproveitstoughness.Inthisstudy,Sc_2O_3wasdopedtoNd_2Zr_2O_7.Thephasestructure,TECsandtoughnessof((Nd_(1-x)Scx))_2Zr_2_O7(x=0,0.025,0.05,0.075,0.1)compoundswereinvestigated.((Nd_(1-x)Scx))_2Zr_2_O7(x=0,0.025,0.05,0.075)exhibitedpyrochlorestructure,while((Nd_(0.9)Sc_(0.1)))_2Zr_2O_7consistedofpyrochloreandfluoritephases.WiththeincreaseoftheSc_2O_3content,theorderingdegreeofthepyrochloreinthecompoundsdecreased.In((Nd_(1-x)Scx))_2Zr_2O_7series,((Nd_(0.925)Sc_(0.075)))_2Zr_2O_7exhibitedthelargestTEC,whilethetoughnessofthecompoundsincreasedwithincreasingtheSc_2O_3content.Therelatedmechanismswerediscussedbasedonthecrystalstructureanalysis.ConsideringtheTECandtoughness,10mol%Sc_2O_3wassuggestedastheoptimaldopingcontentforNd_2Zr_2O_7ceramic.

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简介：Inpursuingexcellentsupercapacitorelectrodes,wedesignedaseriesofM0S2/C0S2compositesconsistingofflower-likedMoS2andoctahedron-shapedCoS2throughafacileone-stephydrothermalmethodandinvestigatedtheelectrochemicalperformanceofthesampleswithvarioushydrothermaltime.Duetothecouplingoftwometalspeciesandabigamountofwell-developedCoS2andMoS2,theresultsindicatedthattheMoS2/CoS2compositeselectrodesexhibitedthebestelectrochemicalperfor-mancewithalargespecificcapacitanceof490F/gat2mV/sor400F/gat10A/gamongallsamplesasthehydrothermaltimereached48h(MCS48).Furthermore,theretentionofMCS48is93.1%after10000cyclesat10A/g,whichmanifeststheexcellentcyclingstability.TheoutstandingelectrochemicalperformanceofMCS48indicatesthatitcouldbeaverypromisingandnovelenergystoragematerialforsupercapacitorsinthefuture.

简介：归纳他我国难熔金属的现状，客观分析了我国加入WTO后难熔金属工业发展的优势，劣势面临的机遇与挑战，提出了我国难熔金属的未来发展对策。

简介：Inthepaper,theauthorsanalysetherela-tionshipbetweentheelectricalconductivityσofZrO2andthecontentofdopedstabilizingagentbythePositronAnnihilationTechnique,andexplainthechangetendencyofσwiththecontentofstabilizingagent.Theresearchshowsthat"numberofeffectivevacancy"inmaterialisadecisivefactorcausingchangeofσ.

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简介：LowcarbonsteelswithBandPadditionswereremeltedbyelectromagneticlevitationandsolidifiedinavacuumdroptube.Thedropletvolumesweresettobe2mm×2mm×2mm(TM)and5mm×5mm×5mm(FM),respectively.Themicrostructureofrapidlysolidifiedsteeldroplets(cooledinsiliconoil)withPandbothBandPadditionwasobserved.ThemicrostructuresofB-bearingdropletsamplesweremoreuniformthanthoseofB-freeones,forbothTMandFMsamples.Thedistributionof℃andPalongthediameterofeachsamplewasdetected.Thewell-distributionof℃andPwasdetectedinB-bearingdropletsamples.SoitcouldbededucedthatBwasalsowelldistributedinthesteels.ItwasBatomsthatpromotedthewell-distributionof℃andP,whichfurtherimprovedtheuniformityofmicrostructureundertheconditionofrapidsolidification.Themicro-hardnessofBbearingsampleswashigherthanthatofB-freesamples,andthehardeningmechanismwasdiscussedindetail.

简介：以正硅酸乙酯和葡萄糖分别作Si源和C源，草酸和硼酸分别作催化剂，采用溶胶一凝胶法制备SiC前驱体，并采用碳热还原法制备纳米SiC。采用XRD、SEM对样品的物相和形貌进行表征。结果表明，用草酸作催化剂制备的前驱体在1550℃制备的SiC是颗粒与晶须的混合体，颗粒粒径为30~50nm，晶须长度为1～3μm，晶须直径为60～100nm；用硼酸作催化剂制备的前驱体其碳热还原温度显著降低，在1400℃就能制备出SiC颗粒与晶须的混合体，颗粒粒径为20~30nm，由于B加入后的抑制作用，SiC晶须的含量明显减少。

简介：PositronannihilationbehaviorshavebeenstudiedinthesinglephaseNd2Fe14BmagnetandthenanocompositeNd2Fe14B/α-Femagnet,preparedbymeltspinning.Theresultsshowedthatthenumberofvacancy-clusteratgrainboundariesincreaseswithincreasingannealingtemperatureforthebothtypesofmagnets.Theincreaseofthiskindofdefectcanimprovethecoercivityof

简介：(Ni0.81Fe0.19)0.66Cr0.34hasahighresistivityandacrystalstructureclosetothatofNi0.81Fe0.19.TheelectricalandX-raydiffractionmeasurementsprovethatathinNiFeCrseedlayerinducesawell(111)-orientedNi0.81Fe0.19film.Post-annealingtreatmentimprovesthemagneticpropertiesof(Ni0.81Fe0.19)0.66Cr0.34(45A)/Ni0.81Fe0.19(150A)/Ta(55A)thinfilmpreparedunderadepositionfield,whereastheinter-diffu-sionofNiFe/Tadeterioratesthemagnetoresistancepropertiesofthefilm.

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简介：MoleculardynamicssimulationusingauniversalforcefieldhasbeenemployedtodeterminethediffusioncoefficientsofO2andNa2SO4vaporintoB2O3andSiCfrom700Kto1273K,respectively.Einsteindiffusionwasobservedina250～300pssimulation.ThediffusioncoefficientfortheO2rangefromabout9.279×10-9cm2/sforB2O3to2.275×10-10cm2/sforSiCataloadingof32moleculespersimulationbox,thatfortheNa2SO4vaporrangefromabout9.888×10-7cm2/sforB2O3to1.837×10-10cm2/sforSiCataloadingof8moleculespersimulationbox.EnvironmentpropertiesofC/SiCcompositewillbeincreasedviatheB2O3preventingthediffusionofO2andNa2SO4vaporintothepyrolyticinterphaseandcarbonfibers.

简介：通过对不同环境状态下实验数据的统计分析，研究采用简单线性回归分析方法和组合Weibull分析方法计算材料许用值的准确性。研究结果表明，与采用Weibull分布方法相比，采用简单线性回归方法或组合weibull分析方法估算复合材料的B基准许用值，可有效提高许用值的准确度。

简介：有alloying原子X=C，B，N，O和空缺的镁和它的合金的概括叠的差错(GSF)精力和表面精力用第一原则的方法被调查了。叠的差错精力上的alloying原子和空缺的占优势的减少效果在slip飞机附近在第一层从他们的位置被结果，这被发现。叠的差错精力是将近与纯镁一样当alloying原子和空缺被放在时第二，第三，第4，第5和第6层。O强烈减少Mg的GSF精力，这被显示出。alloying原子C，B和N增加表面精力，但是O和空缺减少Mg的表面精力。Mg和Mg合金的韧性被使用在表面精力和不稳定的叠差错精力之间的比率基于瑞斯标准讨论了。

简介：ExperimentswerecarriedouttostudytheinfluenceofsurfaceconditiononexpulsionduringthespotweldingofAZ31BMgalloy.AgeneralelectricalcontactresistancetheoryforconductiveroughsurfacesandtherelationbetweenmaximumtemperatureTminthecontactandvoltage-dropVacrossinterfaceoftwosurfaceswereemployedtounderstandthereasonofexpulsioninMgalloyspotwelding.Themainreasonofexpulsionisthatthehighelectricalcontactresistanceinducedbylargeroughnessofthesurfaceandoxidefilmcoveredonthesurfaceleadstolocalmeltingofmetalintheinterfaceoftwosurfaces,andliquidmetalofthelocalareaejectedfromthespecimenunderelectrodeforceformsexpulsion.

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简介：ThehomogeneousplasticflowoffullyamorphousandpartiallycrystallizedZr41.2Ti13.8Cu12.5Ni10Be22.5bulkmetallicglass(Vitl)hasbeeninvestigatedbycompressiontestsathightemperaturesinsupercooledliquidregion.Experimentalresultsshowthatatsufficientlylowstrainrates,thesupercooledliquidofthefullyamorphousalloyrevealsNewtonianflowwithalinearrelationshipbetweentheflowstressandstrainrate.Asthestrainrateisincreased,atransitionfromlinearNewtoniantononlinearflowisdetected,whichcanbeexplainedbythetransitionstatetheory.Overtheentirestrainrateintervalinvestigated,however,onlynonlinearflowispresentinthepartiallycrystallizedalloy,andtheflowstressforeachstrainrateismuchhigher.Itisfoundthatthestrainrate-stressrelationshipforthepartiallycrystallizedalloyatthegiventemperatureof646Kalsoobeysthesinhlawderivedfromthetransitionstatetheory,similartothatoftheinitialhomogeneousamorphousalloy.Thus,itisproposedthattheflowbehaviorofthenanocrystalline/amorphouscompositeat646Kismainlycontrolledbytheviscousflowoftheremainingsupercooledliquid.