简介：Monoammoniumphosphate(1molL^-1),monopotassiumphosphate(1molL^-1)andaluminumchloride(5×10^-3molL^-1)wereusedtoinvestigatetheinfluenceofpHontheformationofNH4-taranakiteandK-taranakiteinsystemswithahighNH4H2PO4orKH2PO4concentration.TheexperimentaldataindicatedthatthereactionproductsofaluminumwithNH4H2PO4orKH2PO4changedwiththepHinthesystems.InapHrangeof2.5to10.0,asthepHincreased,theproductsineitherammoniumorpotassiumsystemfollowedthesequence:taranakite,amorphous(NH4,K)2AIH(PO4)2.4H2O,andthencrystalline(NH4,K)AlPO4OH.2H2O.However,thepHrangesoftheformationoftheseproductsinammoniumsystemweredifferentfrompotassiumsystem.NH4-taranakiteformedfrompH2.75topH5.75,whereasK-taranakiteformedinthepHrangeof3.00to5.0,Fromthetheoreticalcalcuationbyacomputerprogram(GEOCHEMversion2.0),NH4-taranakteandK-taranakitecouldformatthepHfrom1.50to8.30andfrom1.25to8.45,respectively.ThesepHrangesweremuchwiderthantheexperimentalresults.Thedifferencebetweentheexperimentaldataandtheoreticaldatawasattributedtothelackofkineticdataand/ortheincompletenessandinaccuracyofthethermodynamicdatainthedatabaseoftheprogram.ThepHrangesoftheformationofthetaranakitesindicatedthatthetaranakitescouldexistintheimmediatevicinityofphosphateferilizerzoneasreactionproductsofphosphatefertilizerswithsoils,especiallyacideicsoils,resultinginthefixationofnotonlyphosphatebutalsonitrogenand/orpotassiuminsoils.

简介：TheimpactofpHchangesonmicrobialbiomasscarbon(Cmic)andmicrobialbiomassphosphorus(Pmic)wereexaminedfor3redsoilsundercitrusproductionwithdifferentlengthsofcultivation.SoilpHsignificantlyaffectedCmicandPmic.TheCmicandPmicchanges,asafunctionofsoilpH,appearedtofollowanormaldistributionwiththeoriginalsoilpHvalueattheapexandaspHincreasedordecreasedcomparedtotheoriginalsoilpH,CmicandPmicdeclined.Moreover,therewerecriticalpHvaluesatbothextremes(3.0ontheacidicsideand8.0to8.5onthealkalineside),beyondwhichmostofmicroorganismscouldneversurvive.TheeffectofpHonCmicandPmicwasalsorelatedtotheoriginalsoilpH.ThehighertheoriginalsoilpHwas,thelessCmicorPmicwereaffectedbypHchange.ItissuggestedthatsoilmicroorganismsthatgrowinasoilenvironmentwithamoreneutralsoilpHrange(I.e.pH5.5-7.5)mayhaveagreatertolerancetopHchangesthanthosegrowinginmoreacidicormorealkalinesoilpHconditions.

简介：在modulating植物生产率的土壤pH的潜在的角色根据干燥质量被估计，在0.25m2空铅形式收获了，在北希腊的二块低生产率的高地草地使遭到了到年度因素的氮(N)和磷(P)授精(15gNm−2year−1和10gPm−2year−1)在最小上3年的时期。在这些特别条件下面，一种积极关系将在土壤pH和植物生产率之间存在，进一步，营养素的那N或P化肥应用限制系统，这被假设，将导致一变弱这种积极关系。一种重要积极关系在其它在二个学习区域和一个积极趋势之一在土壤pH和植物生产率之间被证实。而且，植物生产率增加，后面的授精，看起来在土壤pH植物生产率关系上有有害效果。调查结果支持原来的假设并且加强想法种调停差异的土壤pH植物生产率关系是发生在更多的“typical”下面的更强烈的植物种形成的结果更高的pH在的土壤条件与热带区域对比适度。