简介：Fivehumicfractionswereobtainedfromauniformly^15N-labelledsoilbyextractionwith0.1molL^-1Na4P2O7,0.1molL^-1NaOH,andHF/HCl-0.1molL^-1NaOH,consecutively,andanalyzedby^13Cand^15NCPMASNMR(crosspolarizationandmagicanglespinningnuclearmagneticresonace).Comparedwiththoseofnativesoilshumicfractionsstudiedasawholecontainedmorealkyls,methoxylsandO-alkyls,being27%-36%,17%-21%and36%-40%,respectively,butfeweraromaticsandcarboxyls(bein14%-20%and13%-90%,respectively),Amongthosehumicfractions,thehumicacid(HA)andfulvicacid(FA)extractedby0.1molL^-1Na4P2O7containedslightlymorecarboxylsthancorrespondinghumicfractionsextractedby0.1molL^-1NaOH,andtheHAextactedby0.1molL^-1NaOHaftertreatmentwithHF/HClcontainedtheleastaromaticsandcarboxyls.Thedistributionofnitrogenfunctionalgroupsofsoilhumicfractionsstudiedwasquitesimilartoeachotherandalsoquitesimilartothatofhumicfractionfromnativesoils.Morethan75%oftotalNineachfractionwasinamidefrom,with9%-13%presentasaromaticand/oraliphaticaminesandtheremainderasheerocyclicN.

简介：Theannualseriesofδ13CweremeasuredintreeringsofthreeCryptomeriafortuneidisks(CF-1,CF-2,andCF-3)collectedfromWestTianmuMountain,ZhejiangProvince,China,accordingtocross-datingtreeringages.Therewasnoobviousdecreasingtrendoftheδ13CannualtimeseriesofCF-2before1835.However,from1835to1982thethreetreeringδ13Cannualseriesexhibitedsimilardecreasingtrendsthatweresignificantly(P≤0.001)correlated.Thedistributioncharacteristicsofascatterdiagrambetweenestimatedδ13CseriesofCF-2frommodelingandtheatmosphericCO2concentrationextractedfromtheLawDomeicecorefrom1840to1978wereanalyzedandacurvilinearregressionequationforreconstructingatmosphericCO2concentrationwasestablishedwithR2=0.98.Also,atestofindependentsamplesindicatedthatbetween1685and1839thereconstructedatmosphericCO2concentrationusingtheδ13CseriesofCF-2hadacloserelationshipwiththeLawDomeandSipleicecores,withastandarddeviationof1.98.ThegeneralincreasingtrendofthereconstructedatmosphericCO2concentrationcloselyreflectedthelong-termvariationofatmosphericCO2concentrationrecordedbothbeforeandaftertheIndustrialRevolution.Between1685and1840theevaluatedatmosphericCO2concentrationwasstable,butafter1840itexhibitedarapidincrease.Givenalongerδ13Cannualtimeseriesoftreerings,itwasfeasibletorebuildarepresentativetimeseriestodescribetheatmosphericCO2concentrationforanearlierperiodandforyearsthatwerenotintheicecorerecord.