简介:Thestrategyofsequentiallyspin-coatingaperovskitefilmfromtheperovskiteprecursorandanelectrontransportinglayerof[6,6]-phenyl-C71-butyricacidmethylester(PC71BM)isdevelopedtosimplifythefabricationprocedureofperovskitesolarcells.X-raydiffractionandscanningelectronmicroscopyindicatethatPC71BMfilmonperovskitelayercanretardtheevaporationofdimethylsulfoxide(DMSO)efficiently,thusprolongingthetransformationofintermediatephasetoperovskitecrystals,leadingtoahighqualityperovskitethinfilm.Thesolarcellswiththestructureofindiumtinoxides(ITO)/poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate)(PEDOT:PSS)/CH3NH3PbI3/PC71BM/bathocuproine(BCP)/Agmadefromthissimplifiedmethodexhibitahigherefficiency(12.68%)thanthosefromtheconventionalone-stepmethod(9.49%).
简介:Theefficiencyofthepoly(3-hexylthiophene)(P3HT)and[6,6]-phenylC61-butyricacidmethylester(PC61BM)basedorganicsolarcellswasenhancedbyusing1,2,4-trichlorobenzene(TCB)asaprocessingadditivetocontroltheblendmorphology.TheadditionofTCBimprovedthearrangementofP3HTwhichresultedingoodphaseseparatedblendfilms.Correspondingly,theoptimizedsolarcellsshowedapowerconversionefficiency(PCE)of4.17%withafillfactor(FF)of0.69,whichwerehigherthanthoseofcommonthermalannealingdevices(PCE3.84%,FF0.67).Theefficiencywasfurtherimprovedto4.74%bythermalannealingat150°Cfor10minwithahigherFFof0.74.
简介:ThetreatmentofsalicylicacidmanufacturingwastewaterbyNDA-100resinwasinvestigated.ThesorptionintensityofphenolwasfoundtobestronglydependentonpHoftheaqueousphase.EquilibriumadsorptiondatafittobothLangmuirandFreundlichmodels.ThecolumnadsorptionshowedthatthisprocesswassuitableforthetreatmentofsalicylicacidmanufacturingwastewaterAbout99.9%CODcrremovalwasobtainedundertheoptimaloperatingconditions.Theresincouldbecompletelyregeneratedwith1BV8%(w/w)NaOH+2BVH2O,therecoveryof98.9%ofthesubstancewasreached.Thisprocessmakesitpossibletorecoverthevaluablematerialfromthewastewaterandtoimprovetheeffluentwaterquality.