学科分类
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1 个结果
  • 简介:Amorphouscarbonandgrapheneco-modifiedLiFePO4nanocompositehasbeensynthesizedviaafacilepolyolprocessinconnectionwithafollowingthermaltreatment.Variouscharacterizationtechniques,includingXRD.Mossbauerspectra,Ramanspectra,SEM,TEM,BET,O2-TPO,galvanocharge-discharge,CVandEISwereappliedtoinvestigatethephasecomposition,carboncontent,morphologicalstructureandelectrochemicalperformanceofthesynthesizedsamples.TheeffectofintroducingwayofcarbonsourcesonthepropertiesandperformanceofLiFePO4/C/graphenecompositewaspaidspecialattention.Underoptimizedsyntheticconditions,highlycrystalizedolivine-typeLiFePO4wassuccessfullyobtainedwithelectronconductiveFe2PandFePasthemainimpurityphases.SEMandTEManalysesdemonstratedthegraphenesheetswererandomlydistributedinsidethesampletocreateanopenstructuredLiFePO4withrespecttographene,whiletheglucosederivedcarbonmainlycoatedoverLiFeP04particleswhicheffectivelyconnectedthegraphenesheetsandLiFePO4particlestoresultinamoreefficientchargetransferprocess.Asaresult,favorableelectrochemicalperformancewasachieved.Theperformanceoftheamorphouscarbon-grapheneco-modifiedLiFePO4wasfurtherprogressivelyimproveduponcyclinginthefirst200cyclestoreachareversiblespecificcapacityashighas97mAh·g-1at10Crate.

  • 标签: 无定形碳 复合材料 多元醇 锂离子电池 石墨 改性