摘要
LowcostsiliconcarbonnanometerpowderwassynthesizedbycarbothermalreductionmethodwithnanometerSiO2andcarbonasrawmaterial.Itssynthesisthermodynamicswerediscussed.TheinfluenceofLaonTG-DSCcurvewasalsoanalyzed.ItindicatedthatthesynthesisprocessofSiCpowderhadtwosteps.InthefirststeptwomedialproductionsofSiOgandCOgformed,andinthesecondstep,β-SiCwasfinallysynthesized.After0.3%Laadded,atthefirststep,theinitiatoryformingtemperatureofproducingSiO(g)andCO(g)declinedfrom1351.4to1250.9℃,andthethermalactivationenergydecreasedfrom223.6to34.7J·g-1;atthesecondsteptheinitiatoryformingtemperatureofsynthesizingβ-SiCpowderdeclinedfrom1526.5to1357.8℃,andthethermalactivationenergydecreasedfrom693.7to295.7J·g-1.WithoutLaadded,thebestsynthesistechnologyforβ-SiCpowderwas1550℃for120min,averagepowderdiameterwasbiggerabout150nm.WithLaadded,thebestsynthesistechnologywas1500℃for120min,averagepowderdiameterwasabout100nm.
出版日期
2007年01月23日（中国期刊网平台首次上网日期，不代表论文的发表时间）
