Investigation of ZSM-5/MCM-41 Composite Molecular Sieve for Reducing Olefin Content of FCC Gasoline-中国期刊网

摘要 <正>ZSM-5/MCM-41compositemolecularsievewaspreparedbythenano-assemblingmethod.TheZSM-5molecularsieve,theMCM-41molecularsieve,theZSM-5/MCM-41mechanicalmixtureandtheZSM-5/MCM-41compositemolecularsievewerecharacterizedbyX-raypowderdiffractometry,N2adsorptionisotherms,temperatureprogrammeddesorptionofammoniaandscanningelectronmicroscopyandtheirpropertieswereanalyzed.UsingFCCgasolineasthefeed,activitiesofdifferentmolecularsievesforreducingolefincontentwereinvestigatedinacontinuoushigh-pressuremicro-reactorunitunderthefollowingconditions:areactiontemperatureof400℃,areactiontimeof2h,aweighthourlyspacevelocityof3h-1,andareactionpressureof2.0MPa.TheresultsshowedthattheHMCM-41molecularsievehadlowreactionperformance,andtheHZSM-5molecularsievedemonstratedhigharomatizationactivity,whiletheZSM-5/MCM-41compositemolecularsieveexhibitedabestolefin-reducingperformancebecauseofitshighisomerizationactivityandmoderatearomatizationactivity.Withalargestolefin-reducmgcapabilityandareasonabledistributionofproducts,thecompositemolecularsievewasmoresuitableforFCCgasolineupgradingcomparedtootherthreecatalysts.

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Investigation of ZSM-5/MCM-41 Composite Molecular Sieve for Reducing Olefin Content of FCC Gasoline

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Investigation of ZSM-5/MCM-41 Composite Molecular Sieve for Reducing Olefin Content of FCC Gasoline

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