摘要
Wepresentamicrowave-assistedone-potpolymerizationwiththree-componentsofalkynes,aldehydesandaminesforthesynthesisofnewamino-functionalizedoptoelectronicpolymers.Thepolymerizationofdiynes（1a-1c）,dialdehydes（2aand2b）anddibenzylaminecatalyzedbyInCl3wascarriedoutsmoothlywithin1hundermicrowaveradiation,yieldingfoursolublepolymerswithhighmolecularweights.TheresultingpolymersP1andP2couldbeeasilydissolvedinalcoholandthusutilizedasthecathodeinterlayerforpolymersolarcells（PSCs）.Comparedwiththecontroldevice,thePSCswithP1andP2asthecathodeinterlayerandPTB7-Th:PC71BMasthephotoactivelayerexhibitedsignificantlyhigherpowerconversionefficiencies（PCEs）of9.49%and9.16%,respectively.Theseresultssuggestthatthispolycouplingreactionisanefficientapproachtoconstructthree-componentpolymersforthepracticalapplications.
出版日期
2017年02月12日（中国期刊网平台首次上网日期，不代表论文的发表时间）
