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Synthesis and Characterization of Trans-1,4-butadiene/Isoprene Copolymers： Determination of Sequence Distribution and Thermal Properties

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摘要 trans-1,4-polybutadiene-co-isoprene共聚物TBIR的二个系列用催化剂系统TiCl被准备<潜水艇class=“a-plus-plus”>4/MgCl2-Ali-Bu在不同反应温度的3。所有二和三个一组顺序分布，数字一般水准顺序长度和共聚物的顺序集中被计算根据<啜class=“a-plus-plus”>13C-NMR系列。温度和到到在TBIR共聚物的链片断的分发上的Ip的异戌二烯Bd的丁二烯的起始的臼齿的比率的影响被讨论。共聚物作文和热性质的关联也被评估，它便于由改变Bd内容和温度控制crystallinity和转变温度的度的理解。

DOI 3j73z7y541/1502653

作者 Xiu-bo Jiang;Qing-fei Zhang;贺爱华

机构地区不详

出处《高分子科学：英文版》 2015年6期

关键词序列分布异戊二烯共聚物丁二烯热性能反式

分类 [理学][高分子化学]

出版日期 2015年06月16日（中国期刊网平台首次上网日期，不代表论文的发表时间）

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高分子科学：英文版

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序列分布异戊二烯共聚物丁二烯热性能反式

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