简介:ThestructureandintrinsicmagneticpropertiesofRFeM(M=VorTi),type1:12,havebeenstudiedbymagneticmeasurementandX-raydiffraction.Theyarebody-centeredtetragonalThMn12structure.Thechangesofcrystallatticeconstantscoincidewiththatoftheirelementradii.Curietemperatureisdecidedmainlybytheexchangeinteractionsof3d-3dand3d-4fatompairs.Thedataobtainedbymean-fieldapproximationagreewellwithexperimentalvalues.ThemagneticmomentcouplinginthesecompoundsforLREisferromagnetic,andforHREisantiferromagnetic.Atlowtemperature,anisotropyfieldisdecidedbyREsublattice.Inthispaper,theinfluenceofmagneticpropertiesofcobaltandnickelreplacingironhasalsobeenstudied.
简介:以88%WC+12%Co混合料粉为原料,采用微波烧结制备WC-12Co硬质合金,研究烧结温度与保温时间对合金密度和硬度以及显微组织的影响。结果表明,在1400~1475℃范围内,随烧结温度升高,WC晶粒长大不明显,合金密度和硬度增大。在1475℃的烧结温度下保温0min,烧结周期1.5~2h,烧结合金的相对密度达99.8%,硬度为87.5HRA,烧结样品显微组织结构均匀,但保温时间超过30min后由于晶粒异常长大以及钴相分布不均匀,导致合金的密度和硬度急剧下降。采用辅助加热材料和保温材料以及设计合理的样品摆放,可降低样品中不同部位的温度梯度,从而获得形状良好的合金样品。
简介:Inthelastthreedecadesnewstrongermodified9%Crsteelshavebeenintroducedinnewpowerplantswithsteamparametersupto300bar(1bar=10~5Pa)and600℃.Inordertofurtherincreasethesteamparametersofsteelbasedpowerplantsuptoatargetvalueof650℃/325baritisnecessarytodoublethecreepstrengthcomparedwithtodaysstrongest9%Crsteels,andatthesametimetheresistanceagainststeamoxidationmustbeimprovedbyadding12%Crtothesteel.However,sofarallattemptstomakestronger12%Crsteelshavebeenunsuccessfulbecausethehighchromiumcontentintroducedseveremicrostructureinstabilitiesinthetestedsteels.Recently,itwasfoundthatthemicrostructureinstabilitiesin11%-12%CrsteelscanbeexplainedbytheprecipitationofcoarseCr(V,Nb)NZ-phases,whichdissolvefine(V,Nb)Nnitrides.AnewpossibilitytousetheZ-phaseforstrengtheningof12%Crsteelshasbeenidentified,andthedevelopmentofstablestrongmartensitic12%Crsteelsbasedonthisconceptisexpectedtoallowtheconstructionof325bar/650℃steampowerplantsallbasedonsteel.